Cas no 55102-19-7 (Ruthenium,chlorohydrotris(triphenylphosphine)-, (TB-5-13)-)
Chlorohydrotris(triphenylphosphine)ruthenium(II) (TB-5-13) is a ruthenium-based coordination complex widely used as a homogeneous catalyst in organic synthesis. Its structure features a ruthenium center coordinated to one chloride ligand, one hydride, and three triphenylphosphine (PPh?) groups, offering excellent stability and reactivity. This complex is particularly effective in hydrogenation, isomerization, and transfer hydrogenation reactions due to its tunable electronic and steric properties. The presence of PPh? ligands enhances solubility in organic solvents, facilitating catalytic applications under mild conditions. Its well-defined geometry and robust performance make it a preferred choice for selective transformations in fine chemical and pharmaceutical synthesis. The compound is typically handled under inert conditions to preserve its catalytic activity.
55102-19-7 structure
Product Name:Ruthenium,chlorohydrotris(triphenylphosphine)-, (TB-5-13)-
CAS No:55102-19-7
MF:C54H45ClP3Ru
MW:923.379395246506
MDL:MFCD00061354
CID:367545
PubChem ID:10855030
Update Time:2025-07-02
Ruthenium,chlorohydrotris(triphenylphosphine)-, (TB-5-13)- Chemical and Physical Properties
Names and Identifiers
-
- Ruthenium,chlorohydrotris(triphenylphosphine)-, (TB-5-13)-
- Chlorohydridotris (triphenylphosphine)Ruthenium (II) toluene adduct
- chlororuthenium,triphenylphosphane
- [ruthenium(hydride)(chloride)(PPh3)3]
- chlorohydridotris(triphenylphosphine)ruthenium
- Chlorohydridotris(triphenylphosphine)ruthenium(II)
- chlorotris(triphenylphosphane)-rhodium(I)
- RuHCl(CO)(PPh3)3
- RuHCl(PPh3)3
- Wilkinson's catalyst
- Chlorohydrotris(triphenylphosphine)ruthenium
- CHLOROHYDRIDOTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II)
- CHLOROHYDRIDOTRIS(TRIPHENYLPHOSPHINE) RUTHENIUM(II) TOLUENE ADDUCT
- chlorohydridotris(triphenylphosphine)-ruthenium(I
- Chlorohydridotris(triphenylphosphine)ruthenium(Ⅱ)
- Chlorohydridotris(triphenylphosphine)ruthenium()
- Chlorohydridotris(triphenylphosphine)ruthenium(II)tolueneadduct,98%
- Chlorohydridotris(triphenylphosphine)rutheniuM (II) toluene adduct,98% (PPh3)3HRuCl
- tris(triphenylphosphine)ruthenium chloride
- Chlorohydridotris(triphenylphosphine)ruthenium( cento)
- 55102-19-7
-
- MDL： MFCD00061354
- Inchi： 1S/3C18H15P.ClH.Ru/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h3*1-15H;1H;/q;;;;+1/p-1
- InChI Key： GZKMGAXTHYGXEO-UHFFFAOYSA-M
- SMILES： P(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1.P(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1.P(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1.Cl[Ru]
Computed Properties
- Exact Mass: 923.14700
- Monoisotopic Mass: 923.146605g/mol
- Isotope Atom Count: 0
- Hydrogen Bond Donor Count: 0
- Hydrogen Bond Acceptor Count: 0
- Heavy Atom Count: 59
- Rotatable Bond Count: 9
- Complexity: 504
- Covalently-Bonded Unit Count: 4
- Defined Atom Stereocenter Count: 0
- Undefined Atom Stereocenter Count : 1
- Defined Bond Stereocenter Count: 0
- Undefined Bond Stereocenter Count: 0
- Surface Charge: 0
- Tautomer Count: nothing
- XLogP3: nothing
- Topological Polar Surface Area: 0?2
Experimental Properties
- Color/Form: Not available
- Melting Point: decomposes at 130℃ [ALD94]
- Flash Point: 113?°C
- PSA: 40.77000
- LogP: 7.33840
- Solubility: Not available
- Sensitiveness: air sensitive
Ruthenium,chlorohydrotris(triphenylphosphine)-, (TB-5-13)- Security Information
- Signal Word：warning
- Hazard Statement： H303May be harmful if swallowed+H313Skin contact may be harmful+H333Inhalation may be harmful to the body
- Warning Statement： P264+P280+P305+P351+P338+P337+P313
- Hazard Category Code： 36/37/38-20/21/22
- Safety Instruction： S26-S36-S37-S39
-
Hazardous Material Identification：
- Risk Phrases：R36/37/38
- Storage Condition：storage at -4℃ (1-2weeks), longer storage period at -20℃ (1-2years)
Ruthenium,chlorohydrotris(triphenylphosphine)-, (TB-5-13)- Pricemore >>
| Related Categories | No. | Product Name | Cas No. | Purity | Specification | Price | update time | Inquiry |
|---|---|---|---|---|---|---|---|---|
| SU ZHOU XIN JIA YUAN HUA XUE Technology Co., Ltd. | 600274-250mg |
Ruthenium,chlorohydrotris(triphenylphosphine)-, (TB-5-13)- |
55102-19-7 | 98% | 250mg |
￥552.0 | 2024-07-19 | |
| SU ZHOU XIN JIA YUAN HUA XUE Technology Co., Ltd. | 600274-1g |
Ruthenium,chlorohydrotris(triphenylphosphine)-, (TB-5-13)- |
55102-19-7 | 98% | 1g |
￥1656.0 | 2024-07-19 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | 93-4401-250mg |
Ruthenium,chlorohydrotris(triphenylphosphine)-, (TB-5-13)- |
55102-19-7 | 98% | 250mg |
655.0CNY | 2021-07-10 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | 93-4401-1g |
Ruthenium,chlorohydrotris(triphenylphosphine)-, (TB-5-13)- |
55102-19-7 | 98% | 1g |
1966.0CNY | 2021-07-10 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | B-KD459-1g |
Ruthenium,chlorohydrotris(triphenylphosphine)-, (TB-5-13)- |
55102-19-7 | 98+% | 1g |
1614.0CNY | 2021-07-10 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | B-KD459-50mg |
Ruthenium,chlorohydrotris(triphenylphosphine)-, (TB-5-13)- |
55102-19-7 | 98+% | 50mg |
162.0CNY | 2021-07-10 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | B-KD459-200mg |
Ruthenium,chlorohydrotris(triphenylphosphine)-, (TB-5-13)- |
55102-19-7 | 98+% | 200mg |
461.0CNY | 2021-07-10 | |
| SHANG HAI JI ZHI SHENG HUA Technology Co., Ltd. | T54780-100mg |
Tris(triphenylphosphoranyl)ruthenium(V) chloride hydride |
55102-19-7 | 98% | 100mg |
￥265.0 | 2024-07-18 | |
| SHANG HAI JI ZHI SHENG HUA Technology Co., Ltd. | T54780-5g |
Tris(triphenylphosphoranyl)ruthenium(V) chloride hydride |
55102-19-7 | 98% | 5g |
￥5204.0 | 2024-07-18 | |
| SHANG HAI JI ZHI SHENG HUA Technology Co., Ltd. | T54780-1g |
Tris(triphenylphosphoranyl)ruthenium(V) chloride hydride |
55102-19-7 | 98% | 1g |
￥1487.0 | 2024-07-18 |
Ruthenium,chlorohydrotris(triphenylphosphine)-, (TB-5-13)- Related Literature
-
Xingqun Zheng,Lele Song,Xin Feng,Li Li,Zidong Wei J. Mater. Chem. A, 2020,8, 14145-14151
-
Gloria Belén Ramírez-Rodríguez,José Manuel Delgado-López,Jaime Gómez-Morales CrystEngComm, 2013,15, 2206-2212
-
3. Estimation of hydrogen sulfide from crude petroleum: a unique invention using a simple chemosensor?Shampa Kundu,Prithidipa Sahoo New J. Chem., 2019,43, 12369-12374
-
Domenico Lombardo,Gianmarco Munaò,Pietro Calandra,Luigi Pasqua,Maria Teresa Caccamo Phys. Chem. Chem. Phys., 2019,21, 11983-11991
-
Saeideh Mirfakhraei,Malak Hekmati,Fereshteh Hosseini Eshbala,Hojat Veisi New J. Chem., 2018,42, 1757-1761
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