Cas no 37095-26-4 (Chloro[tris(2,3,4,5,6-pentafluorophenyl)phoshine]gold(I))

Chloro[tris(2,3,4,5,6-pentafluorophenyl)phosphine]gold(I) is a highly specialized organometallic compound featuring a gold(I) center coordinated by a chloro ligand and a tris(pentafluorophenyl)phosphine group. The electron-withdrawing pentafluorophenyl substituents enhance the Lewis acidity of the gold center, making it a potent catalyst for selective transformations, including hydrofunctionalization and cyclization reactions. Its stability under ambient conditions and solubility in common organic solvents facilitate handling and application in homogeneous catalysis. The compound’s robust performance in gold-mediated processes, coupled with its predictable reactivity, makes it valuable for synthetic organic and organometallic chemistry research. Its structural features also allow for mechanistic studies in gold-catalyzed reactions.
Chloro[tris(2,3,4,5,6-pentafluorophenyl)phoshine]gold(I) structure
37095-26-4 structure
Product Name:Chloro[tris(2,3,4,5,6-pentafluorophenyl)phoshine]gold(I)
CAS No:37095-26-4
MF:C18AuClF15P
MW:764.56196975708
CID:2602239
PubChem ID:329764873
Update Time:2025-05-20

Chloro[tris(2,3,4,5,6-pentafluorophenyl)phoshine]gold(I) Chemical and Physical Properties

Names and Identifiers

    • Chloro[tris(2,3,4,5,6-pentafluorophenyl)phoshine]gold(I)
    • DTXSID00467937
    • SCHEMBL19469286
    • AGN-PC-00AS4L
    • 37095-26-4
    • chlorogold;tris(2,3,4,5,6-pentafluorophenyl)phosphane
    • MDL: MFCD18252667
    • Inchi: 1S/C18F15P.Au.ClH/c19-1-4(22)10(28)16(11(29)5(1)23)34(17-12(30)6(24)2(20)7(25)13(17)31)18-14(32)8(26)3(21)9(27)15(18)33;;/h;;1H/q;+1;/p-1
    • InChI Key: NPDADBDFEWCWRT-UHFFFAOYSA-M
    • SMILES: [Au]Cl.P(C1C(=C(C(=C(C=1F)F)F)F)F)(C1C(=C(C(=C(C=1F)F)F)F)F)C1C(=C(C(=C(C=1F)F)F)F)F

Computed Properties

  • Exact Mass: 763.885232g/mol
  • Monoisotopic Mass: 763.885232g/mol
  • Isotope Atom Count: 0
  • Hydrogen Bond Donor Count: 0
  • Hydrogen Bond Acceptor Count: 15
  • Heavy Atom Count: 36
  • Rotatable Bond Count: 3
  • Complexity: 568
  • Covalently-Bonded Unit Count: 2
  • Defined Atom Stereocenter Count: 0
  • Undefined Atom Stereocenter Count : 0
  • Defined Bond Stereocenter Count: 0
  • Undefined Bond Stereocenter Count: 0
  • Topological Polar Surface Area: 0

Experimental Properties

  • Melting Point: 222-226?°C

Chloro[tris(2,3,4,5,6-pentafluorophenyl)phoshine]gold(I) Security Information

  • Symbol: GHS07
  • Signal Word:Warning
  • Hazard Statement: H315-H319-H335
  • Warning Statement: P261-P305+P351+P338
  • Hazardous Material transportation number:NONH for all modes of transport
  • WGK Germany:3
  • Hazard Category Code: 36/37/38
  • Safety Instruction: 26
  • Hazardous Material Identification: Xi

Chloro[tris(2,3,4,5,6-pentafluorophenyl)phoshine]gold(I) Pricemore >>

Related Categories No. Product Name Cas No. Purity Specification Price update time Inquiry
XI GE MA AO DE LI QI ( SHANG HAI ) MAO YI Co., Ltd.
734128-250MG
Chloro[tris(2,3,4,5,6-pentafluorophenyl)phoshine]gold(I)
37095-26-4
250MG
930.54 2021-05-17

Additional information on Chloro[tris(2,3,4,5,6-pentafluorophenyl)phoshine]gold(I)

Chloro[tris(2,3,4,5,6-pentafluorophenyl)phoshine]gold(I) (CAS No. 37095-26-4): Properties, Applications, and Market Insights

Chloro[tris(2,3,4,5,6-pentafluorophenyl)phoshine]gold(I) (CAS No. 37095-26-4) is a highly specialized organometallic compound that has garnered significant attention in recent years due to its unique chemical properties and versatile applications. This gold(I) complex, featuring a tris(2,3,4,5,6-pentafluorophenyl)phoshine ligand, is widely used in catalysis, materials science, and pharmaceutical research. Its stability and reactivity make it a valuable tool for synthetic chemists and industrial researchers alike.

The compound's structure consists of a gold(I) center coordinated to a chlorine atom and a tris(pentafluorophenyl)phoshine ligand. The presence of electron-withdrawing pentafluorophenyl groups enhances the ligand's stability and influences the gold center's electronic properties. This unique combination makes Chloro[tris(2,3,4,5,6-pentafluorophenyl)phoshine]gold(I) particularly effective in catalytic transformations, including cross-coupling reactions and C-H activation processes.

Recent advancements in green chemistry have highlighted the potential of gold(I) complexes like this one as sustainable alternatives to traditional catalysts. Researchers are exploring its use in environmentally friendly synthetic routes, aligning with the global push toward greener industrial processes. The compound's ability to facilitate reactions under mild conditions reduces energy consumption and minimizes waste generation, addressing key concerns in modern chemical manufacturing.

In the pharmaceutical sector, Chloro[tris(2,3,4,5,6-pentafluorophenyl)phoshine]gold(I) has shown promise in the development of novel therapeutic agents. Its unique electronic properties enable selective transformations of complex molecules, making it valuable for drug discovery programs. The compound's stability in biological environments has also sparked interest in medicinal chemistry applications, particularly in the design of targeted therapies.

The materials science community has adopted CAS 37095-26-4 for creating advanced functional materials. Its incorporation into polymers and nanomaterials has led to materials with enhanced optical and electronic properties. These developments are particularly relevant to the growing fields of organic electronics and photovoltaics, where gold-based compounds play a crucial role in improving device performance.

Market analysis indicates increasing demand for specialized gold(I) catalysts like this compound, driven by expanding applications in fine chemical synthesis and materials engineering. The global shift toward more efficient and selective catalytic systems has positioned Chloro[tris(pentafluorophenyl)phoshine]gold(I) as a valuable commodity in the chemical industry. Manufacturers are responding to this demand by developing improved synthetic routes and purification methods for this compound.

Quality control and characterization of 37095-26-4 are critical aspects of its production and application. Advanced analytical techniques, including NMR spectroscopy and X-ray crystallography, are routinely employed to verify the compound's purity and structural integrity. These quality assurance measures ensure consistent performance in research and industrial applications, maintaining the compound's reputation as a reliable reagent.

Storage and handling recommendations for Chloro[tris(2,3,4,5,6-pentafluorophenyl)phoshine]gold(I) emphasize protection from moisture and light to maintain stability. While the compound exhibits good shelf life under proper conditions, users should follow standard laboratory safety protocols when working with this material. The development of stabilized formulations has further enhanced its practicality for various applications.

Recent publications have highlighted innovative uses of tris(pentafluorophenyl)phoshine gold complexes in asymmetric synthesis and chiral induction. These applications leverage the compound's ability to create stereogenic centers with high enantioselectivity, addressing the pharmaceutical industry's need for single-enantiomer drugs. Such developments demonstrate the ongoing evolution of this compound's utility in modern chemistry.

The future outlook for CAS No. 37095-26-4 appears promising, with research continuing to uncover new applications and improved synthetic methodologies. As sustainable chemistry practices gain momentum, the demand for efficient and selective catalysts like this gold(I) complex is expected to grow. Ongoing studies are exploring its potential in emerging fields such as energy storage and conversion, further expanding its industrial relevance.

For researchers considering Chloro[tris(2,3,4,5,6-pentafluorophenyl)phoshine]gold(I) for their projects, numerous commercial sources offer this compound in various quantities and purities. Comparative studies of different suppliers' products can help identify the most suitable option for specific applications. The compound's relatively straightforward synthesis also makes it accessible to laboratories with appropriate capabilities.

In conclusion, 37095-26-4 represents a versatile and valuable tool in modern chemical research and industrial applications. Its unique combination of stability and reactivity, coupled with growing interest in gold-catalyzed transformations, ensures its continued importance in the chemical sciences. As research progresses, new applications for this remarkable compound are likely to emerge, further solidifying its position in the chemist's toolbox.

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