Cas no 35789-03-8 (Tris[N,N-bis(trimethylsilyl)amide]gadolinium(III))
Tris[N,N-bis(trimethylsilyl)amide]gadolinium(III) is a highly reactive, thermally stable gadolinium coordination complex, commonly employed in advanced chemical synthesis and materials science. Its key advantages include strong Lewis acidity, making it useful in catalytic applications, and its robust silylamide ligands, which enhance solubility in nonpolar solvents. The compound is particularly valuable in the deposition of gadolinium-containing thin films via chemical vapor deposition (CVD) or atomic layer deposition (ALD), owing to its volatility and clean decomposition profile. Additionally, its moisture sensitivity necessitates handling under inert conditions, ensuring high purity in specialized synthetic processes. This reagent is favored in organometallic and inorganic chemistry for its precise reactivity and structural uniformity.
![Tris[N,N-bis(trimethylsilyl)amide]gadolinium(III) structure](https://ossimg.kuujia.com/scimg/36000/35789-03-8x500.png)
35789-03-8 structure
Product Name:Tris[N,N-bis(trimethylsilyl)amide]gadolinium(III)
CAS No:35789-03-8
MF:C18H54GdN3Si6
MW:638.404469966888
MDL:MFCD03427091
CID:89168
PubChem ID:24878983
Update Time:2025-06-06
Tris[N,N-bis(trimethylsilyl)amide]gadolinium(III) Chemical and Physical Properties
Names and Identifiers
-
- Tris[N,N-bis(trimethylsilyl)amide]gadolinium(III)
- gadolinium tris(1,1,1,3,3,3-hexamethyldisilazan-2-ide)
- GADOLINIUM TRIS(HEXAMETHYLDISILAZIDE)
- TRIS(N N-BIS(TRIMETHYLSILYL)AMIDE)GADO&
- Gadolinium tris[bis(trimethylsilyl)amide]
- DTXSID80404002
- 35789-03-8
- Gadolinium(III) tris[N,N-bis(trimethylsilyl)amide]
- bis(trimethylsilyl)azanide;gadolinium(3+)
-
- MDL： MFCD03427091
- Inchi： 1S/3C6H18NSi2.Gd/c3*1-8(2,3)7-9(4,5)6;/h3*1-6H3;/q3*-1;+3
- InChI Key： LFWPRLGQJJEPDP-UHFFFAOYSA-N
- SMILES： [Gd+3].[Si](C)(C)(C)[N-][Si](C)(C)C.[Si](C)(C)(C)[N-][Si](C)(C)C.[Si](C)(C)(C)[N-][Si](C)(C)C
Computed Properties
- Exact Mass: 638.21700
- Monoisotopic Mass: 638.21744g/mol
- Isotope Atom Count: 0
- Hydrogen Bond Donor Count: 0
- Hydrogen Bond Acceptor Count: 3
- Heavy Atom Count: 28
- Rotatable Bond Count: 6
- Complexity: 297
- Covalently-Bonded Unit Count: 4
- Defined Atom Stereocenter Count: 0
- Undefined Atom Stereocenter Count : 0
- Defined Bond Stereocenter Count: 0
- Undefined Bond Stereocenter Count: 0
- Surface Charge: 0
- Tautomer Count: nothing
- XLogP3: nothing
- Topological Polar Surface Area: 3?2
Experimental Properties
- Color/Form: powder
- Melting Point: 67-90?°C (lit.)
- Boiling Point: 126°C at 760 mmHg
- Flash Point: Fahrenheit: 35.6 ° f
Celsius: 2 ° c - Water Partition Coefficient: Soluble in water.
- PSA: 9.72000
- LogP: 7.26750
- Solubility: React with water
- Sensitiveness: Moisture Sensitive
- Vapor Pressure: No data available
Tris[N,N-bis(trimethylsilyl)amide]gadolinium(III) Security Information
-
Symbol:
- Signal Word：Danger
- Hazard Statement： H228-H261-H314
- Warning Statement： P210-P231+P232-P280-P305+P351+P338-P310-P422
- Hazardous Material transportation number：UN 3396 4.3/PG 2
- WGK Germany：3
- Hazard Category Code： 11-14/15-34
- Safety Instruction： S16; S26; S36/37/39; S43; S45; S7/8
-
Hazardous Material Identification：
- Safety Term：4.1
- Packing Group：III
- Risk Phrases：R11; R14/15; R34
- HazardClass：4.1
- PackingGroup：III
- Storage Condition：Moisture Sensitive. Ambient temperatures.
Tris[N,N-bis(trimethylsilyl)amide]gadolinium(III) Pricemore >>
| Related Categories | No. | Product Name | Cas No. | Purity | Specification | Price | update time | Inquiry |
|---|---|---|---|---|---|---|---|---|
| XI GE MA AO DE LI QI （ SHANG HAI ） MAO YI Co., Ltd. | 547824-1G |
Tris[N,N-bis(trimethylsilyl)amide]gadolinium(III) |
35789-03-8 | 98% | 1G |
￥1180.18 | 2022-02-24 | |
| A FA AI SHA ， SAI MO FEI SHI ER KE JI QI XIA GONG SI | 44359-1g |
Tris[N,N-bis(trimethylsilyl)amide]gadolinium(III), 98% |
35789-03-8 | 98% | 1g |
￥1428.00 | 2023-07-11 | |
| A FA AI SHA ， SAI MO FEI SHI ER KE JI QI XIA GONG SI | 44359-5g |
Tris[N,N-bis(trimethylsilyl)amide]gadolinium(III), 98% |
35789-03-8 | 98% | 5g |
￥7140.00 | 2023-07-11 | |
| abcr | AB204444-1 g |
Tris[N,N-bis(trimethylsilyl)amide]gadolinium(III), 98%; . |
35789-03-8 | 98% | 1 g |
€121.40 | 2023-07-20 | |
| abcr | AB204444-5 g |
Tris[N,N-bis(trimethylsilyl)amide]gadolinium(III), 98%; . |
35789-03-8 | 98% | 5 g |
€419.00 | 2023-07-20 | |
| SHANG HAI HAO HONG Biomedical Technology Co., Ltd. | 1440712-1g |
Tris[N,N-bis(trimethylsilyl)amide]gadolinium(III), 98% |
35789-03-8 | 98% | 1g |
￥1281.00 | 2024-05-17 | |
| Cooke Chemical | F648322-1g |
Tris[N,N-bis(trimethylsilyl)amide]gadolinium(III) |
35789-03-8 | 98 | 1g |
RMB 1269.60 | 2025-02-21 | |
| Cooke Chemical | F648322-5g |
Tris[N,N-bis(trimethylsilyl)amide]gadolinium(III) |
35789-03-8 | 98 | 5g |
RMB 5078.40 | 2025-02-21 | |
| SHENG KE LU SI SHENG WU JI SHU | sc-255710-1 g |
Tris[N,N-Bis(trimethylsilyl)amide]gadolinium(III), |
35789-03-8 | 1g |
￥948.00 | 2023-07-10 | ||
| SHENG KE LU SI SHENG WU JI SHU | sc-255710-1g |
Tris[N,N-Bis(trimethylsilyl)amide]gadolinium(III), |
35789-03-8 | 1g |
￥948.00 | 2023-09-05 |
Tris[N,N-bis(trimethylsilyl)amide]gadolinium(III) Suppliers
Amadis Chemical Company Limited
Gold Member
Audited Supplier
(CAS:35789-03-8)Tris[N,N-bis(trimethylsilyl)amide]gadolinium(III)
Order Number:A1210022
Stock Status:in Stock
Quantity:5g
Purity:99%
Pricing Information Last Updated:Monday, 2 September 2024 15:58
Price ($):261.0
Email:[email protected]
Tris[N,N-bis(trimethylsilyl)amide]gadolinium(III) Related Literature
-
Gloria Belén Ramírez-Rodríguez,José Manuel Delgado-López,Jaime Gómez-Morales CrystEngComm, 2013,15, 2206-2212
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Zhiyan Chen,Nan Wu,Yaobing Wang,Bing Wang,Yingde Wang J. Mater. Chem. A, 2018,6, 516-526
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Yi Cao,Yujiao Xiahou,Lixiang Xing,Xiang Zhang,Hong Li,ChenShou Wu,Haibing Xia Nanoscale, 2020,12, 20456-20466
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Yaling Zhang,Chunhui Dai,Shiwei Zhou,Bin Liu Chem. Commun., 2018,54, 10092-10095
35789-03-8 (Tris[N,N-bis(trimethylsilyl)amide]gadolinium(III)) Related Products
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Recommended suppliers
Amadis Chemical Company Limited
(CAS:35789-03-8)Tris[N,N-bis(trimethylsilyl)amide]gadolinium(III)
Purity:99%
Quantity:5g
Price ($):261.0