Cas no 3491-12-1 (4,4-( p-Phenylenedioxy)dianiline)

4,4'-(p-Phenylenedioxy)dianiline is a high-purity aromatic diamine compound characterized by its symmetrical structure and functional amine groups. Its key advantages include excellent thermal stability and chemical resistance, making it suitable for high-performance polymer applications such as polyimides, epoxy resins, and other advanced thermosetting materials. The compound’s rigid aromatic backbone contributes to enhanced mechanical properties and dimensional stability in synthesized polymers. Its reactivity with various electrophilic reagents allows for versatile use in crosslinking and curing processes. Additionally, it serves as a valuable intermediate in the production of specialty coatings, adhesives, and composites where durability and high-temperature performance are critical. Proper handling is advised due to its amine functionality.
4,4-( p-Phenylenedioxy)dianiline structure
3491-12-1 structure
Product Name:4,4-( p-Phenylenedioxy)dianiline
CAS No:3491-12-1
MF:C18H16N2O2
MW:292.331844329834
MDL:MFCD00039153
CID:44220
PubChem ID:87564179
Update Time:2025-10-23

4,4-( p-Phenylenedioxy)dianiline Chemical and Physical Properties

Names and Identifiers

    • 1,4-Bis(4-aminophenoxy)benzene
    • 1,4-Phenylene-di-4-aminophenyl ether
    • 4,4’-(1,4-phenlenebis(oxy))bis-benzenamin
    • 4-[4-(4-Aminophenoxy)phenoxy]phenylamine
    • Benzenamine,4,4'-[1,4-phenylenebis(oxy)]bis-
    • p,p’-(p-phenylenedioxy)di-anilin
    • RODA
    • TPE-Q
    • 4,4'-(P-PHENYLENEDIOXY)DIANILINE
    • HYDROQUINONE BIS(4-AMINOPHENYL) ETHER
    • APB-134
    • APB-144
    • Aniline, p,p'-(p-phenylenedioxy)di-
    • Bisaminophenoxybenzene
    • 1,4-BIS(4-AMINOPHENOXY)BENZENE(144BAPB)
    • 4,4'-(1,4-Phenylenedioxy)dianiline
    • 1,4-Bis(4-aminophenoxyl) benzene
    • 1,4-Bis-(4-aminophenoxy)-benzene
    • 1,4'-bis(p-aminophenoxy)benzene
    • 4,4'-(1,4-phenylenebis(oxy))dibenzenamine
    • 4,4'-(1,4-phenylenebisoxy)dianiline
    • ANILINE,p,p'-(p-PHENYLENEDIOXY)DI
    • Aniline,4,4'-(p-phenylenedioxy)di- (6CI,7CI,8CI)
    • 1,4-Bis(p-aminophenoxy)benzene
    • 4,4'-[1,4-Phenylenebis(oxy)]bis[aniline]
    • 4,4'-[1,4-Phenylenebis(oxy)]bis[benzenamine]
    • p-Bis(4-aminophenoxy)benzene
    • p-Phenylenebis(oxy-p-phenylene)diamine
    • 4-[4-(4-aminophenoxy)phenoxy]aniline
    • 1,4-Phenylenedi(4-aminophenyl ether)
    • JCRRFJIVUPSNTA-UHFFFAOYSA-N
    • Benzenamine, 4,4'-[1,4-phenylenebis(oxy)]bis-
    • 4,4'-(1,4-Phenylenebis(oxy))dianiline
    • Oprea1_095445
    • Benzenamine, 4,4'-(1,4-phenlenebis(oxy))bis-
    • InChI=1/C18H16N2O2/c19-13-1-5-15(6-2-13)21-17-9-11-18(12-10-17)22-16-7-3-14(20)4-8-16/h1-12H,19-20H2
    • SCHEMBL65211
    • 4-[4-(4-Aminophenoxy)phenoxy]phenylamine #
    • 3491-12-1
    • 4-[4-(4-aminophenoxy)phenoxy]aniline;1,4-Bis-(4-aminophenoxy)-benzene
    • EU-0066968
    • B1243
    • CS-W009994
    • F10185
    • CCRIS 6685
    • AKOS003242083
    • YSWG196
    • FT-0606784
    • SB66821
    • BRN 0422398
    • NS00122462
    • AS-14366
    • JCRRFJIVUPSNTA-UHFFFAOYSA-
    • A822466
    • DTXSID70188465
    • MFCD00039153
    • DB-002369
    • 4,4-( p-Phenylenedioxy)dianiline
    • MDL: MFCD00039153
    • Inchi: 1S/C18H16N2O2/c19-13-1-5-15(6-2-13)21-17-9-11-18(12-10-17)22-16-7-3-14(20)4-8-16/h1-12H,19-20H2
    • InChI Key: JCRRFJIVUPSNTA-UHFFFAOYSA-N
    • SMILES: O(C1C=CC(=CC=1)N)C1C=CC(=CC=1)OC1C=CC(=CC=1)N
    • BRN: 0422398

Computed Properties

  • Exact Mass: 292.12100
  • Monoisotopic Mass: 292.121178
  • Isotope Atom Count: 0
  • Hydrogen Bond Donor Count: 2
  • Hydrogen Bond Acceptor Count: 4
  • Heavy Atom Count: 22
  • Rotatable Bond Count: 4
  • Complexity: 283
  • Covalently-Bonded Unit Count: 1
  • Defined Atom Stereocenter Count: 0
  • Undefined Atom Stereocenter Count : 0
  • Defined Bond Stereocenter Count: 0
  • Undefined Bond Stereocenter Count: 0
  • Surface Charge: 0
  • XLogP3: 2.9
  • Topological Polar Surface Area: 70.5

Experimental Properties

  • Color/Form: Not determined
  • Density: 1.243
  • Melting Point: 173.0 to 177.0 deg-C
  • Boiling Point: 437.6°C at 760 mmHg
  • Flash Point: 267.8°C
  • Refractive Index: 1.667
  • PSA: 70.50000
  • LogP: 5.59800
  • Solubility: Not determined
  • Sensitiveness: Sensitive to air

4,4-( p-Phenylenedioxy)dianiline Security Information

4,4-( p-Phenylenedioxy)dianiline Customs Data

  • HS CODE:2922299090
  • Customs Data:

    China Customs Code:

    2922299090

    Overview:

    2922299090. Other amino groups(naphthol\phenol)And ether\Esters [including their salts, Except those containing more than one oxygen-containing group]. VAT:17.0%. Tax refund rate:13.0%. Regulatory conditions:nothing. MFN tariff:6.5%. general tariff:30.0%

    Declaration elements:

    Product Name, component content, use to, The color of ethanolamine and its salt should be reported, The package of ethanolamine and its salt shall be declared

    Summary:

    2922299090. other amino-naphthols and other amino-phenols, other than those containing more than one kind of oxygen function, their ethers and esters; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

4,4-( p-Phenylenedioxy)dianiline Pricemore >>

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4,4-( p-Phenylenedioxy)dianiline Suppliers

Suzhou Senfeida Chemical Co., Ltd
Gold Member
Audited Supplier Audited Supplier
(CAS:3491-12-1)1,4-Bis(4-aminophenoxy)benzene
Order Number:1647813;sfd15216
Stock Status:in Stock
Quantity:Company Customization/200kg
Purity:98%/99.9%
Pricing Information Last Updated:Monday, 14 April 2025 21:49
Price ($):discuss personally
Tiancheng Chemical (Jiangsu) Co., Ltd
Gold Member
Audited Supplier Audited Supplier
(CAS:3491-12-1)1,4-雙(4-氨基苯氧基)苯
Order Number:LE1647813
Stock Status:in Stock
Quantity:25KG,200KG,1000KG
Purity:99%
Pricing Information Last Updated:Friday, 20 June 2025 12:31
Price ($):discuss personally

4,4-( p-Phenylenedioxy)dianiline Related Literature

Additional information on 4,4-( p-Phenylenedioxy)dianiline

4,4'-(p-Phenylenedioxy)dianiline (CAS No. 3491-12-1): A Versatile Building Block for High-Performance Polymers

4,4'-(p-Phenylenedioxy)dianiline (CAS No. 3491-12-1) is an important aromatic diamine compound that serves as a key intermediate in the synthesis of advanced polymer materials. With the growing demand for high-temperature resistant polymers and specialty polyimides, this compound has gained significant attention in both industrial and research applications.

The molecular structure of 4,4'-(p-Phenylenedioxy)dianiline features two amine groups connected through a diphenyl ether linkage, which contributes to its unique properties. This configuration makes it particularly valuable for creating thermally stable polymers with excellent mechanical strength and chemical resistance - properties highly sought after in aerospace, electronics, and automotive industries.

Recent trends in green chemistry and sustainable materials have highlighted the importance of compounds like 4,4'-(p-Phenylenedioxy)dianiline. Researchers are exploring its use in developing bio-based polyimides and recyclable polymer systems, addressing common questions about how to balance performance with environmental considerations in material science.

In the field of electronic packaging materials, this diamine has shown promise for creating low-dielectric constant polymers, a hot topic as the electronics industry seeks solutions for 5G technology and advanced semiconductor packaging. The compound's ability to form crosslinked networks with various dianhydrides makes it particularly valuable for these applications.

The synthesis and applications of 4,4'-(p-Phenylenedioxy)dianiline frequently appear in searches related to polyimide precursors and high-performance polymer intermediates. Many researchers inquire about its solubility characteristics, thermal stability range, and compatibility with different curing agents - all critical factors for material formulation.

From a commercial perspective, the global market for specialty diamines like 4,4'-(p-Phenylenedioxy)dianiline is experiencing steady growth, driven by increasing demand from the flexible electronics sector and advanced composite materials industry. Manufacturers are focusing on developing more efficient production methods to meet this growing demand while maintaining high purity standards.

In research laboratories, scientists are investigating novel derivatives of 4,4'-(p-Phenylenedioxy)dianiline to create polymers with tailored properties. This includes work on self-healing materials and shape-memory polymers - two areas generating significant interest in materials science circles. The compound's molecular flexibility allows for various modifications while maintaining its core beneficial characteristics.

Quality control aspects of 4,4'-(p-Phenylenedioxy)dianiline production are another frequent search topic, with professionals seeking information about analytical methods for purity determination and storage conditions to maintain product stability. These practical considerations are crucial for ensuring consistent performance in downstream applications.

As the push for lightweight materials continues across multiple industries, the role of 4,4'-(p-Phenylenedioxy)dianiline-based polymers becomes increasingly important. Its ability to contribute to both mechanical strength and weight reduction makes it particularly valuable for applications where these properties are paramount, such as in aerospace components and high-performance sporting goods.

The future development of 4,4'-(p-Phenylenedioxy)dianiline applications appears promising, with ongoing research exploring its potential in energy storage materials and advanced coatings. As material requirements become more stringent and specialized, this versatile compound is likely to find even broader utility in cutting-edge technological applications.

Recommended suppliers
Suzhou Senfeida Chemical Co., Ltd
(CAS:3491-12-1)1,4-Bis(4-aminophenoxy)benzene
1647813;sfd15216
Purity:98%/99.9%
Quantity:Company Customization/200kg
Price ($):Inquiry/Inquiry
Email
Tiancheng Chemical (Jiangsu) Co., Ltd
(CAS:3491-12-1)1,4-雙(4-氨基苯氧基)苯
LE1647813
Purity:99%
Quantity:25KG,200KG,1000KG
Price ($):Inquiry
Email