Cas no 32993-05-8 (Cyclopentadienylbis(triphenylphosphine)ruthenium Chloride)

Cyclopentadienylbis(triphenylphosphine)ruthenium Chloride is a ruthenium-based organometallic compound with the formula [(C?H?)Ru(PPh?)?Cl]. This complex is notable for its stability and versatility in catalytic applications, particularly in hydrogenation, transfer hydrogenation, and C–C coupling reactions. The cyclopentadienyl (Cp) ligand provides robust coordination to the ruthenium center, while the triphenylphosphine (PPh?) ligands enhance solubility in organic solvents and modulate reactivity. Its well-defined structure and air stability make it a reliable precursor for synthetic and mechanistic studies in organometallic chemistry. The compound is particularly useful in homogeneous catalysis, offering controlled reactivity and selectivity for fine chemical synthesis.
Cyclopentadienylbis(triphenylphosphine)ruthenium Chloride structure
32993-05-8 structure
Product Name:Cyclopentadienylbis(triphenylphosphine)ruthenium Chloride
CAS No:32993-05-8
MF:C41H35ClP2Ru
MW:726.187131166458
MDL:MFCD00075004
CID:53990
PubChem ID:87559913
Update Time:2025-10-28

Cyclopentadienylbis(triphenylphosphine)ruthenium Chloride Chemical and Physical Properties

Names and Identifiers

    • Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)
    • Chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium(II)
    • Cyclopentadienylbis(triphenylphosphine)ruthenium(II) Chloride
    • Bis(triphenylphosphine)(chloro)cyclopentadienylruthenium
    • Chloro(Cydopentadienyl) bis (Triphenyl-
    • Chlorocyclopentadienylbis(triphenylphosphine)rutenium(II)
    • Chlorocyclopentadienylbis(triphenylphosphine)-ruthenium(II)
    • Cyclopentadienylbis(triphenylphosphine)ruthenium Chloride
    • (Ph3P)2(cyclopentadienyl)RuCl
    • [ClRu(PPh3)2Cp]
    • [Cp(PPh3)2RuCl]
    • Chloro(cyclopentadienyl)bis(triphenylphosphine)ruthe
    • chlorocyclopentadienylbis(triphenylphosphine)ruthenium
    • Chlorocyclopentadienylbis(triphenylphosphine)rutheniuM(II) 5GR
    • Chlorocyclopentadienylbis-(triphenylphosphino)-ruthenium
    • CpRu(PPh3)2Cl
    • Cyclopentadienyl
    • Bis(triphenylphosphine)cyclopentadienylruthenium chloride
    • Ruthenium,chloro-p-cyclopentadienylbis(triphenylphosphine)-(8CI)
    • Chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium
    • Chloro(h-cyclopentadienyl)bis(triphenylphosphine)ruthenium
    • Chloro(h5-2,4-cyclopentadien-1-yl)bis(triphenylphosphine)ruthenium
    • Chloro(h5-cyclopentadienyl)bis(triphenylphosphine)ruthenium
    • Chloro-p-cyclopentadienylbis(triphenylphosphine)ruthenium
    • h5-Cyclopentadienylbis(triphenylphosphine)rutheniumchloride
    • Chloro(cyclopentadienyl) bis(triphenylphosphine) ruthenium(II)
    • 32993-05-8
    • FT-0696282
    • MFCD00075004
    • AC-5527
    • AKOS025310720
    • cyclopenta-2,4-dien-1-ide; bis(triphenylphosphane); lambda2-chloranidylrutheniumbis(ylium)
    • MDL: MFCD00075004
    • Inchi: 1S/2C18H15P.C5H5.ClH.Ru/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2-4-5-3-1;;/h2*1-15H;1-5H;1H;/q;;;;+1/p-1
    • InChI Key: YUYGUQQDGRTJMA-UHFFFAOYSA-M
    • SMILES: [Ru]Cl.P(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1.P(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1.[CH]1C=CC=C1 |^1:40|

Computed Properties

  • Exact Mass: 726.09500
  • Monoisotopic Mass: 726.094593g/mol
  • Isotope Atom Count: 0
  • Hydrogen Bond Donor Count: 0
  • Hydrogen Bond Acceptor Count: 0
  • Heavy Atom Count: 45
  • Rotatable Bond Count: 6
  • Complexity: 242
  • Covalently-Bonded Unit Count: 4
  • Defined Atom Stereocenter Count: 0
  • Undefined Atom Stereocenter Count : 0
  • Defined Bond Stereocenter Count: 0
  • Undefined Bond Stereocenter Count: 0
  • Topological Polar Surface Area: 0?2

Experimental Properties

  • Color/Form: solid
  • Melting Point: 135?°C (dec.) (lit.)
  • Boiling Point: No data available
  • Water Partition Coefficient: dissolution
  • PSA: 27.18000
  • LogP: 8.60060
  • Solubility: Soluble in water
  • Sensitiveness: Air & Moisture Sensitive

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Cyclopentadienylbis(triphenylphosphine)ruthenium Chloride Production Method

Cyclopentadienylbis(triphenylphosphine)ruthenium Chloride Suppliers

Amadis Chemical Company Limited
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(CAS:32993-05-8)Cyclopentadienylbis(triphenylphosphine)ruthenium Chloride
Order Number:A875461
Stock Status:in Stock
Quantity:25.0g/50.0g/100.0g
Purity:99%
Pricing Information Last Updated:Friday, 30 August 2024 09:46
Price ($):153.0/289.0/561.0

Additional information on Cyclopentadienylbis(triphenylphosphine)ruthenium Chloride

Comprehensive Overview of Cyclopentadienylbis(triphenylphosphine)ruthenium Chloride (CAS No. 32993-05-8)

Cyclopentadienylbis(triphenylphosphine)ruthenium Chloride (CAS No. 32993-05-8) is a highly specialized organometallic compound that has garnered significant attention in both academic and industrial research. This compound, often abbreviated as [CpRu(PPh3)2Cl], is a versatile catalyst and precursor in various chemical transformations. Its unique structure, featuring a cyclopentadienyl ligand and two triphenylphosphine groups coordinated to a ruthenium center, makes it a valuable tool in synthetic chemistry.

The compound's applications span a wide range of fields, including homogeneous catalysis, organic synthesis, and materials science. Researchers are particularly interested in its role in C-H activation and hydrogenation reactions, which are critical for developing sustainable chemical processes. With the growing demand for green chemistry and renewable energy solutions, Cyclopentadienylbis(triphenylphosphine)ruthenium Chloride has become a focal point for innovation.

One of the most frequently searched questions about this compound is: "What are the catalytic applications of Cyclopentadienylbis(triphenylphosphine)ruthenium Chloride?" The answer lies in its ability to facilitate selective bond formation and functional group transformations. For instance, it is widely used in olefin metathesis, a reaction that has revolutionized polymer chemistry and pharmaceutical synthesis. Its stability and reactivity under mild conditions make it a preferred choice for fine chemical production.

Another hot topic in the scientific community is the compound's potential in photocatalysis. With the rise of solar energy conversion technologies, researchers are exploring how ruthenium-based complexes like Cyclopentadienylbis(triphenylphosphine)ruthenium Chloride can be used to harness sunlight for chemical reactions. This aligns with the global push toward carbon-neutral and energy-efficient processes.

The synthesis and handling of Cyclopentadienylbis(triphenylphosphine)ruthenium Chloride require expertise due to its sensitivity to air and moisture. However, advancements in air-free techniques and schlenk line methodologies have made it more accessible to researchers. Its CAS No. 32993-05-8 is a key identifier for sourcing high-purity samples, ensuring reproducibility in experimental results.

In summary, Cyclopentadienylbis(triphenylphosphine)ruthenium Chloride (CAS No. 32993-05-8) is a cornerstone in modern organometallic chemistry. Its multifaceted applications, from catalysis to energy storage, underscore its importance in addressing contemporary scientific challenges. As research continues to evolve, this compound will undoubtedly remain at the forefront of innovation.

Recommended suppliers
Amadis Chemical Company Limited
(CAS:32993-05-8)Cyclopentadienylbis(triphenylphosphine)ruthenium Chloride
A875461
Purity:99%/99%/99%
Quantity:25.0g/50.0g/100.0g
Price ($):153.0/289.0/561.0
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