Cas no 32993-05-8 (Cyclopentadienylbis(triphenylphosphine)ruthenium Chloride)
Cyclopentadienylbis(triphenylphosphine)ruthenium Chloride Chemical and Physical Properties
Names and Identifiers
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- Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)
- Chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium(II)
- Cyclopentadienylbis(triphenylphosphine)ruthenium(II) Chloride
- Bis(triphenylphosphine)(chloro)cyclopentadienylruthenium
- Chloro(Cydopentadienyl) bis (Triphenyl-
- Chlorocyclopentadienylbis(triphenylphosphine)rutenium(II)
- Chlorocyclopentadienylbis(triphenylphosphine)-ruthenium(II)
- Cyclopentadienylbis(triphenylphosphine)ruthenium Chloride
- (Ph3P)2(cyclopentadienyl)RuCl
- [ClRu(PPh3)2Cp]
- [Cp(PPh3)2RuCl]
- Chloro(cyclopentadienyl)bis(triphenylphosphine)ruthe
- chlorocyclopentadienylbis(triphenylphosphine)ruthenium
- Chlorocyclopentadienylbis(triphenylphosphine)rutheniuM(II) 5GR
- Chlorocyclopentadienylbis-(triphenylphosphino)-ruthenium
- CpRu(PPh3)2Cl
- Cyclopentadienyl
- Bis(triphenylphosphine)cyclopentadienylruthenium chloride
- Ruthenium,chloro-p-cyclopentadienylbis(triphenylphosphine)-(8CI)
- Chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium
- Chloro(h-cyclopentadienyl)bis(triphenylphosphine)ruthenium
- Chloro(h5-2,4-cyclopentadien-1-yl)bis(triphenylphosphine)ruthenium
- Chloro(h5-cyclopentadienyl)bis(triphenylphosphine)ruthenium
- Chloro-p-cyclopentadienylbis(triphenylphosphine)ruthenium
- h5-Cyclopentadienylbis(triphenylphosphine)rutheniumchloride
- Chloro(cyclopentadienyl) bis(triphenylphosphine) ruthenium(II)
- 32993-05-8
- FT-0696282
- MFCD00075004
- AC-5527
- AKOS025310720
- cyclopenta-2,4-dien-1-ide; bis(triphenylphosphane); lambda2-chloranidylrutheniumbis(ylium)
-
- MDL: MFCD00075004
- Inchi: 1S/2C18H15P.C5H5.ClH.Ru/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2-4-5-3-1;;/h2*1-15H;1-5H;1H;/q;;;;+1/p-1
- InChI Key: YUYGUQQDGRTJMA-UHFFFAOYSA-M
- SMILES: [Ru]Cl.P(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1.P(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1.[CH]1C=CC=C1 |^1:40|
Computed Properties
- Exact Mass: 726.09500
- Monoisotopic Mass: 726.094593g/mol
- Isotope Atom Count: 0
- Hydrogen Bond Donor Count: 0
- Hydrogen Bond Acceptor Count: 0
- Heavy Atom Count: 45
- Rotatable Bond Count: 6
- Complexity: 242
- Covalently-Bonded Unit Count: 4
- Defined Atom Stereocenter Count: 0
- Undefined Atom Stereocenter Count : 0
- Defined Bond Stereocenter Count: 0
- Undefined Bond Stereocenter Count: 0
- Topological Polar Surface Area: 0?2
Experimental Properties
- Color/Form: solid
- Melting Point: 135?°C (dec.) (lit.)
- Boiling Point: No data available
- Water Partition Coefficient: dissolution
- PSA: 27.18000
- LogP: 8.60060
- Solubility: Soluble in water
- Sensitiveness: Air & Moisture Sensitive
Cyclopentadienylbis(triphenylphosphine)ruthenium Chloride Security Information
-
Symbol:
- Prompt:warning
- Signal Word:Warning
- Hazard Statement: H302+H312+H332-H315-H319
- Warning Statement: P261-P264-P270-P271-P280-P301+P312+P330-P302+P352+P312+P362+P364-P304+P340+P312-P305+P351+P338+P337+P313-P501
- Hazardous Material transportation number:NONH for all modes of transport
- WGK Germany:3
- Hazard Category Code: 20/21/22-36/37/38
- Safety Instruction: 26-37/39-36/37/39-22
-
Hazardous Material Identification:
- Safety Term:S22;S26;S36/37/39
- Risk Phrases:R20/21/22; R36/37/38
- Storage Condition:Store at room temperature
Cyclopentadienylbis(triphenylphosphine)ruthenium Chloride Pricemore >>
| Related Categories | No. | Product Name | Cas No. | Purity | Specification | Price | update time | Inquiry |
|---|---|---|---|---|---|---|---|---|
| SHANG HAI A LA DING SHENG HUA KE JI GU FEN Co., Ltd. | C118505-1g |
Cyclopentadienylbis(triphenylphosphine)ruthenium Chloride |
32993-05-8 | 98% | 1g |
¥604.90 | 2023-09-03 | |
| SHANG HAI A LA DING SHENG HUA KE JI GU FEN Co., Ltd. | C118505-25g |
Cyclopentadienylbis(triphenylphosphine)ruthenium Chloride |
32993-05-8 | 98% | 25g |
¥8651.90 | 2023-09-03 | |
| SHANG HAI A LA DING SHENG HUA KE JI GU FEN Co., Ltd. | C118505-5g |
Cyclopentadienylbis(triphenylphosphine)ruthenium Chloride |
32993-05-8 | 98% | 5g |
¥2467.90 | 2023-09-03 | |
| Chemenu | CM102958-5g |
Chloro(1,3-cyclopentadien-1-yl)ruthenium-triphenylphosphine(1:2) |
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| Alichem | A019117586-10g |
Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II) |
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| TRC | C988290-1g |
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$ 125.00 | 2022-06-06 | ||
| TRC | C988290-2.5g |
Cyclopentadienylbis(triphenylphosphine)ruthenium Chloride |
32993-05-8 | 2.5g |
$ 260.00 | 2022-06-06 | ||
| TRC | C988290-10g |
Cyclopentadienylbis(triphenylphosphine)ruthenium Chloride |
32993-05-8 | 10g |
$ 825.00 | 2022-06-06 | ||
| SHANG HAI YI EN HUA XUE JI SHU Co., Ltd. | R020255-1g |
Cyclopentadienylbis(triphenylphosphine)ruthenium Chloride |
32993-05-8 | 97% | 1g |
¥68 | 2023-09-09 | |
| SHANG HAI YI EN HUA XUE JI SHU Co., Ltd. | R020255-5g |
Cyclopentadienylbis(triphenylphosphine)ruthenium Chloride |
32993-05-8 | 97% | 5g |
¥248 | 2023-09-09 |
Cyclopentadienylbis(triphenylphosphine)ruthenium Chloride Suppliers
Cyclopentadienylbis(triphenylphosphine)ruthenium Chloride Related Literature
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Yaling Zhang,Chunhui Dai,Shiwei Zhou,Bin Liu Chem. Commun., 2018,54, 10092-10095
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Weili Dai,Guangjun Wu,Michael Hunger Chem. Commun., 2015,51, 13779-13782
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Jason Y. C. Lim,Yong Yu,Guorui Jin,Kai Li,Yi Lu,Jianping Xie Nanoscale Adv., 2020,2, 3921-3932
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Hongxia Li,Aikifa Raza,Qiaoyu Ge,Jin-You Lu,TieJun Zhang Soft Matter, 2020,16, 6841-6849
Additional information on Cyclopentadienylbis(triphenylphosphine)ruthenium Chloride
Comprehensive Overview of Cyclopentadienylbis(triphenylphosphine)ruthenium Chloride (CAS No. 32993-05-8)
Cyclopentadienylbis(triphenylphosphine)ruthenium Chloride (CAS No. 32993-05-8) is a highly specialized organometallic compound that has garnered significant attention in both academic and industrial research. This compound, often abbreviated as [CpRu(PPh3)2Cl], is a versatile catalyst and precursor in various chemical transformations. Its unique structure, featuring a cyclopentadienyl ligand and two triphenylphosphine groups coordinated to a ruthenium center, makes it a valuable tool in synthetic chemistry.
The compound's applications span a wide range of fields, including homogeneous catalysis, organic synthesis, and materials science. Researchers are particularly interested in its role in C-H activation and hydrogenation reactions, which are critical for developing sustainable chemical processes. With the growing demand for green chemistry and renewable energy solutions, Cyclopentadienylbis(triphenylphosphine)ruthenium Chloride has become a focal point for innovation.
One of the most frequently searched questions about this compound is: "What are the catalytic applications of Cyclopentadienylbis(triphenylphosphine)ruthenium Chloride?" The answer lies in its ability to facilitate selective bond formation and functional group transformations. For instance, it is widely used in olefin metathesis, a reaction that has revolutionized polymer chemistry and pharmaceutical synthesis. Its stability and reactivity under mild conditions make it a preferred choice for fine chemical production.
Another hot topic in the scientific community is the compound's potential in photocatalysis. With the rise of solar energy conversion technologies, researchers are exploring how ruthenium-based complexes like Cyclopentadienylbis(triphenylphosphine)ruthenium Chloride can be used to harness sunlight for chemical reactions. This aligns with the global push toward carbon-neutral and energy-efficient processes.
The synthesis and handling of Cyclopentadienylbis(triphenylphosphine)ruthenium Chloride require expertise due to its sensitivity to air and moisture. However, advancements in air-free techniques and schlenk line methodologies have made it more accessible to researchers. Its CAS No. 32993-05-8 is a key identifier for sourcing high-purity samples, ensuring reproducibility in experimental results.
In summary, Cyclopentadienylbis(triphenylphosphine)ruthenium Chloride (CAS No. 32993-05-8) is a cornerstone in modern organometallic chemistry. Its multifaceted applications, from catalysis to energy storage, underscore its importance in addressing contemporary scientific challenges. As research continues to evolve, this compound will undoubtedly remain at the forefront of innovation.
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