Cas no 32305-98-9 ((-)-DIOP)
(-)-DIOP structure
Product Name:(-)-DIOP
CAS No:32305-98-9
MF:C31H32O2P2
MW:498.532110214233
MDL:MFCD00014107
CID:88961
PubChem ID:24854261
Update Time:2025-04-18
(-)-DIOP Chemical and Physical Properties
Names and Identifiers
-
- (((4R,5R)-2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(methylene))bis(diphenylphosphine)
- (-)-DIOP
- (-)-2,3-O-Isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)
- (4R,5R)-(-)-4,5-Bis(diphenylphosphinomethyl)-2,2-dimethyl-1,3-dioxolane
- (2R,3R)-(-)-1,4-Bis(diphenylphosphino)-2,3-O-isopropylidene-2,3-butanediol
- (-)-2,3-O-Isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)butane
- (?)-2,3-O-Isopropylidene-2,3-dihydroxy-1,4-bis(dipheny
- (?)-2,3-O-Isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)butane
- (2R,3R)-(-)-2,3-O-Isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)butane
- MLV 3077D
- (R,R)-DIOP
- (4R,5R)-(-)-Bis(diphenylphosphinomethyl)-2,2-dimethyl-1,3-dioxolane
- (4R,5R)-4,5-Bis(diphenylphosphinomethyl)-2,2-dimethyl-1,3-dioxolane
- (4R,5R)-DIOP
- (4R,5R)-trans-4,5-Bis[(diphenylphosphino)methyl]-2,2-dimethyl-1,3-dioxolane
- (R)-DIOP
- [[(4R,5R)-2,2-Dimethyl-1,3-dioxolane-4,5-diyl]bis(methylene)]bis[diphenylphosphine]
-
- MDL： MFCD00014107
- Inchi： 1S/C31H32O2P2/c1-31(2)32-29(23-34(25-15-7-3-8-16-25)26-17-9-4-10-18-26)30(33-31)24-35(27-19-11-5-12-20-27)28-21-13-6-14-22-28/h3-22,29-30H,23-24H2,1-2H3/t29-,30-/m0/s1
- InChI Key： VCHDBLPQYJAQSQ-KYJUHHDHSA-N
- SMILES： P(C1C=CC=CC=1)(C1C=CC=CC=1)C[C@H]1[C@H](CP(C2C=CC=CC=2)C2C=CC=CC=2)OC(C)(C)O1
- BRN： 1441045
Computed Properties
- Exact Mass: 498.18800
- Isotope Atom Count: 0
- Hydrogen Bond Donor Count: 0
- Hydrogen Bond Acceptor Count: 2
- Heavy Atom Count: 35
- Rotatable Bond Count: 8
- Complexity: 528
- Covalently-Bonded Unit Count: 1
- Defined Atom Stereocenter Count: 0
- Undefined Atom Stereocenter Count : 2
- Defined Bond Stereocenter Count: 0
- Undefined Bond Stereocenter Count: 0
- Surface Charge: 0
- XLogP3: 6.2
- Topological Polar Surface Area: 18.5
Experimental Properties
- Color/Form: White powder
- Melting Point: 88-90?°C (lit.)
- Solubility: Insuluble (2.1E-5 g/L) (25 oC),
- PSA: 45.64000
- LogP: 5.77230
- Sensitiveness: Air Sensitive
- Specific Rotation: -26° (c 2.0, CHCl3)
- Optical Activity: [α]19/D ?26°, c =?2.3 in chloroform
- Solubility: Not determined
(-)-DIOP Security Information
-
Symbol:
- Prompt：warning
- Signal Word：Warning
- Hazard Statement： H315-H319-H335
- Warning Statement： P261-P305+P351+P338
- Hazardous Material transportation number：NONH for all modes of transport
- WGK Germany：3
- Hazard Category Code： 36/37/38
- Safety Instruction： S26; S36/37
- FLUKA BRAND F CODES：10-23
-
Hazardous Material Identification：
- Storage Condition：2-8°C
- Risk Phrases：R36/37/38
(-)-DIOP Customs Data
- HS CODE：2932999099
- Customs Data：
China Customs Code:
2932999099Overview:
2932999099. Other heterocyclic compounds containing only oxygen heteroatoms. VAT:17.0%. Tax refund rate:13.0%. Regulatory conditions:nothing. MFN tariff:6.5%. general tariff:20.0%
Declaration elements:
Product Name, component content, use to
Summary:
2932999099. other heterocyclic compounds with oxygen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%
(-)-DIOP Pricemore >>
| Related Categories | No. | Product Name | Cas No. | Purity | Specification | Price | update time | Inquiry |
|---|---|---|---|---|---|---|---|---|
| SU ZHOU XIN JIA YUAN HUA XUE Technology Co., Ltd. | 600395-1g |
(-)-DIOP |
32305-98-9 | 99% | 1g |
￥285.0 | 2024-07-19 | |
| SU ZHOU XIN JIA YUAN HUA XUE Technology Co., Ltd. | 600395-250mg |
(-)-DIOP |
32305-98-9 | 99% | 250mg |
￥100.0 | 2024-07-19 | |
| Alichem | A159001614-1g |
(((4R,5R)-2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(methylene))bis(diphenylphosphine) |
32305-98-9 | 95% | 1g |
$236.38 | 2023-09-02 | |
| Alichem | A159001614-5g |
(((4R,5R)-2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(methylene))bis(diphenylphosphine) |
32305-98-9 | 95% | 5g |
$729.24 | 2023-09-02 | |
| Chemenu | CM196480-1g |
(((4R,5R)-2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(methylene))bis(diphenylphosphine) |
32305-98-9 | 95% | 1g |
$209 | 2021-08-05 | |
| Chemenu | CM196480-5g |
(((4R,5R)-2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(methylene))bis(diphenylphosphine) |
32305-98-9 | 95% | 5g |
$662 | 2021-08-05 | |
| Chemenu | CM196480-1g |
(((4R,5R)-2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(methylene))bis(diphenylphosphine) |
32305-98-9 | 95% | 1g |
$*** | 2023-03-29 | |
| Chemenu | CM196480-5g |
(((4R,5R)-2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(methylene))bis(diphenylphosphine) |
32305-98-9 | 95% | 5g |
$*** | 2023-03-29 | |
| SHANG HAI MAI KE LIN SHENG HUA Technology Co., Ltd. | O815299-250mg |
(-)-2,3-O-Isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino) |
32305-98-9 | 97% | 250mg |
￥246.00 | 2022-09-01 | |
| abcr | AB121583-250 mg |
(4R,5R)-(-)-4,5-Bis(diphenylphosphinomethyl)-2,2-dimethyl-1,3-dioxolane, 99.5% (R,R)-DIOP; . |
32305-98-9 | 99.5% | 250 mg |
€76.20 | 2023-07-20 |
(-)-DIOP Suppliers
Tiancheng Chemical (Jiangsu) Co., Ltd
Gold Member
Audited Supplier
(CAS:32305-98-9)(2R,3R)-(-)-1,4-雙(二苯基膦基)-2,3-O-異亞丙基-2,3-丁二醇
Order Number:LE1730111
Stock Status:in Stock
Quantity:25KG,200KG,1000KG
Purity:99%
Pricing Information Last Updated:Friday, 20 June 2025 12:35
Price ($):discuss personally
Email:[email protected]
Amadis Chemical Company Limited
Gold Member
Audited Supplier
(CAS:32305-98-9)(-)-DIOP
Order Number:A821227
Stock Status:in Stock
Quantity:5g/25g
Purity:99%
Pricing Information Last Updated:Friday, 30 August 2024 05:13
Price ($):153.0/760.0
Email:[email protected]
(-)-DIOP Related Literature
-
Yam N. Timsina,Rakesh K. Sharma,T. V. RajanBabu Chem. Sci. 2015 6 3994
-
2. The reaction of trimethylsilyldiazomethane with complexes of the type [PtX(CH3)(diphosphine)] (X?=?Cl, Br, I). Some observations on β-hydrogen migrations in PtCHRCH3 species and organoplatinum(II)-catalysts for alkene formation from trimethylsilyldiazomethanePaola Bergamini,Emiliana Costa,Christian Ganter,A. Guy Orpen,Paul G. Pringle J. Chem. Soc. Dalton Trans. 1999 861
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Alexander Kraynov,Ryan Richards Phys. Chem. Chem. Phys. 2007 9 884
-
Alexander Kraynov,Ryan Richards Phys. Chem. Chem. Phys. 2007 9 884
-
Barry M. Trost,Xiaoxun Li Chem. Sci. 2017 8 6815
32305-98-9 ((-)-DIOP) Related Products
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- 57221-94-0([5-[Bis(2-methylphenyl)phosphanylmethyl]-2,2-dimethyl-1,3-dioxolan-4-yl]methyl-bis(2-methylphenyl)phosphane)
- 220196-29-2(Phosphine,[[(4R,5R)-2,2-dimethyl-1,3-dioxolane-4,5-diyl]bis(methylene)]bis[bis(3,5-dimethylphenyl)-,rel-(+)- (9CI))
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- 78764-37-1(Phosphonium, triphenyl[2-(2,2,4-trimethyl-1,3-dioxolan-4-yl)ethyl]-, iodide (1:1))
- 402846-61-1((4-(2,2-Dimethyl-1,3-dioxolan-4-yl)butyl)triphenylphosphonium bromide)
