Cas no 3225-26-1 (4-Hydroxy-TEMPO Benzoate, Free Radical)
4-Hydroxy-TEMPO Benzoate, Free Radical Chemical and Physical Properties
Names and Identifiers
-
- 1-Piperidinyloxy,4-(benzoyloxy)-2,2,6,6-tetramethyl-
- 4-Hydroxy-2,2,6,6-tetramethylpiperidine 1-Oxyl Benzoate Free Radical[Catalyst for Oxidation]
- (1-λ<sup>1</sup>-oxidanyl-2,2,6,6-tetramethylpiperidin-4-yl) benzoate
- 1-oxyl-2,2,6,6-tetramethlpiperidin-4-yl benzoate
- 4-Benzoyloxy-2,2,6,6-tetramethylpiperidine 1-Oxyl Free Radical
- 4-benzoyloxy-2,2,6,6-tetramethylpiperidine-1-oxy
- 4-benzoyloxy-2,2,6,6-tetramethylpiperidine-1-oxyl
- 4-benzoyloxy-2,6-tetramethylpiperidine-N-oxyl
- 4-Benzoyloxy-TEMPO
- 4-Benzoyloxy-TEMPO Free Radical
- 4-Hydroxy-2,2,6,6-tetramethylpiperidine 1-oxyl benzoate
- 4-Hydroxy-TEMPO benzoate,free radical
- 4-Hydroxy-TEMPO-benzoate
- 4-PhCO2-TEMPO
- 4-Hydroxy-TEMPO Benzoate Free Radical
- [4-(Benzoyloxy)-2,2,6,6-tetramethyl-1-piperidinyl]oxidanyl
- CHEBI:180676
- 4-Hydroxy-TEMPO benzoate
- AKOS015889094
- 4-Benzoyloxy-2,2,6,6-tetramethylpiperidine 1-Oxyl
- DTXSID20385861
- H0878
- MFCD00075563
- SR-01000209976
- 4-Hydroxy-TEMPO-benzoat
- 4-Benzoyloxy-2,2,6,6-tetramethylpiperidinyloxyl
- 2,2,6,6-Tetramethyl-4-(benzoyloxy)piperidine-1-oxyl
- FT-0618752
- B-0840
- 4-Hydroxy-TEMPO benzoate, free radical, 97%
- SR-01000209976-1
- 3225-26-1
- 4-HYDROXY-TEMPO BENZOATE, FREE RADICAL
- 4-Benzoyloxy-2,2,6,6-tetramethylpiperidinyloxy, free radical~4-Hydroxy-TEMPO benzoate, free radical
- 4-Benzyloxy-TEMPO,freeradical
- 4-Hydroxy-TEMPO Benzoate, Free Radical
-
- MDL: MFCD00075563
- Inchi: 1S/C16H22NO3/c1-15(2)10-13(11-16(3,4)17(15)19)20-14(18)12-8-6-5-7-9-12/h5-9,13H,10-11H2,1-4H3
- InChI Key: MJEDTBDGYVATPI-UHFFFAOYSA-N
- SMILES: O(C(C1C=CC=CC=1)=O)C1CC(C)(C)N(C(C)(C)C1)[O] |^1:19|
- BRN: 1431263
Computed Properties
- Exact Mass: 276.16000
- Monoisotopic Mass: 276.16
- Isotope Atom Count: 0
- Hydrogen Bond Donor Count: 0
- Hydrogen Bond Acceptor Count: 2
- Heavy Atom Count: 20
- Rotatable Bond Count: 3
- Complexity: 341
- Covalently-Bonded Unit Count: 1
- Defined Atom Stereocenter Count: 0
- Undefined Atom Stereocenter Count : 0
- Defined Bond Stereocenter Count: 0
- Undefined Bond Stereocenter Count: 0
- Surface Charge: 0
- Tautomer Count: nothing
- XLogP3: 3.1
- Topological Polar Surface Area: 30.5A^2
Experimental Properties
- Color/Form: Not available
- Density: 1.1±0.1 g/cm3
- Melting Point: 99-101?°C (lit.)
- Boiling Point: 376.8±31.0 °C at 760 mmHg
- Flash Point: 181.7±24.8 °C
- Stability/Shelf Life: Stable. Incompatible with strong oxidizing agents.
- PSA: 29.54000
- LogP: 3.14840
- Solubility: Not available
- Vapor Pressure: 0.0±0.9 mmHg at 25°C
4-Hydroxy-TEMPO Benzoate, Free Radical Security Information
- Signal Word:warning
- Hazard Statement: H303 may be harmful by ingestion +h313 may be harmful by skin contact +h1106 may be harmful by inhalation
-
Warning Statement:
P264 wash thoroughly after treatment
p280 wear protective gloves / wear protective clothing / wear protective eye masks / wear protective masks
p305 if in eyes
p351 rinse carefully with water for a few minutes
p338 remove contact lenses (if any) and easy to operate, continue rinsing
p337 if eye irritation persists
p1086 get medical advice / care - Hazardous Material transportation number:NONH for all modes of transport
- WGK Germany:3
- Hazard Category Code: 36/37/38
- Safety Instruction: S22-S24/25
- Risk Phrases:R36/37/38
- Safety Term:S26;S36
- Storage Condition:4° CStore…,-4℃Store…Better
4-Hydroxy-TEMPO Benzoate, Free Radical Pricemore >>
| Related Categories | No. | Product Name | Cas No. | Purity | Specification | Price | update time | Inquiry |
|---|---|---|---|---|---|---|---|---|
| Fluorochem | 013607-1g |
4-Hydroxy-TEMPO-benzoate |
3225-26-1 | >97.0%(GC) | 1g |
£25.00 | 2022-03-01 | |
| Ambeed | A564526-250mg |
2,2,6,6-Tetramethyl-4-(benzoyloxy)piperidine-1-oxyl |
3225-26-1 | 98% | 250mg |
$34.0 | 2025-02-21 | |
| Ambeed | A564526-1g |
2,2,6,6-Tetramethyl-4-(benzoyloxy)piperidine-1-oxyl |
3225-26-1 | 98% | 1g |
$44.0 | 2025-02-21 | |
| Ambeed | A564526-5g |
2,2,6,6-Tetramethyl-4-(benzoyloxy)piperidine-1-oxyl |
3225-26-1 | 98% | 5g |
$113.0 | 2025-02-21 | |
| Ambeed | A564526-25g |
2,2,6,6-Tetramethyl-4-(benzoyloxy)piperidine-1-oxyl |
3225-26-1 | 98% | 25g |
$557.0 | 2025-02-21 | |
| TRC | H977023-100mg |
4-Hydroxy-TEMPO Benzoate, Free Radical |
3225-26-1 | 100mg |
$ 58.00 | 2023-09-07 | ||
| TRC | H977023-500mg |
4-Hydroxy-TEMPO Benzoate, Free Radical |
3225-26-1 | 500mg |
$ 121.00 | 2023-09-07 | ||
| TRC | H977023-1g |
4-Hydroxy-TEMPO Benzoate, Free Radical |
3225-26-1 | 1g |
$ 190.00 | 2023-09-07 | ||
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | H0878-5g |
4-Hydroxy-TEMPO Benzoate, Free Radical |
3225-26-1 | 97.0%(GC) | 5g |
¥1690.0 | 2022-05-30 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | H0878-1g |
4-Hydroxy-TEMPO Benzoate, Free Radical |
3225-26-1 | 97.0%(GC) | 1g |
¥630.0 | 2022-05-30 |
4-Hydroxy-TEMPO Benzoate, Free Radical Suppliers
4-Hydroxy-TEMPO Benzoate, Free Radical Related Literature
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Kaleem-ur-Rahman Naveed,Li Wang,Haojie Yu,Raja Summe Ullah,Muhammad Haroon,Shah Fahad,Jiyang Li,Tarig Elshaarani,Rizwan Ullah Khan,Ahsan Nazir Polym. Chem. 2018 9 3306
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Hiroyuki Itoi,Hiroyuki Muramatsu,Michio Inagaki RSC Adv. 2019 9 22823
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Kathryn Holguin,Motahareh Mohammadiroudbari,Kaiqiang Qin,Chao Luo J. Mater. Chem. A 2021 9 19083
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4. EPR studies on the organization of self-assembled spin-labeled organic monolayers adsorbed on GaAsSharon Ruthstein,Reit Artzi,Daniella Goldfarb,Ron Naaman Phys. Chem. Chem. Phys. 2005 7 524
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Yuqing Qin,Fei Peng,Yonggang Hu Green Chem. 2019 21 2286
Related Categories
- Solvents and Organic Chemicals Organic Compounds Benzenoids Benzene and substituted derivatives Benzoic acid esters
- Solvents and Organic Chemicals Organic Compounds Benzenoids Benzene and substituted derivatives Benzoic acids and derivatives Benzoic acid esters
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Additional information on 4-Hydroxy-TEMPO Benzoate, Free Radical
4-Hydroxy-TEMPO Benzoate, Free Radical: A Comprehensive Overview
The compound with CAS No 3225-26-1, commonly referred to as 4-Hydroxy-TEMPO Benzoate, is a highly specialized chemical entity that has garnered significant attention in the fields of organic chemistry, materials science, and pharmaceutical research. This compound is notable for its unique structure and functional properties, particularly its role as a free radical species. In this article, we delve into the latest research findings and applications of 4-Hydroxy-TEMPO Benzoate, highlighting its significance in modern scientific advancements.
4-Hydroxy-TEMPO Benzoate is a derivative of TEMPO (tert-butyl hydroperoxide), a well-known oxidizing agent. The introduction of the hydroxyl group at the fourth position of the benzoate ring imparts unique electronic and steric properties to the molecule. Recent studies have demonstrated that this modification enhances the compound's stability and reactivity, making it an ideal candidate for various applications in radical chemistry. The ability of 4-Hydroxy-TEMPO Benzoate to act as a free radical has been extensively explored in the context of polymerization reactions and redox processes.
The synthesis of CAS No 3225-26-1 involves a multi-step process that combines traditional organic synthesis techniques with modern catalytic methods. Researchers have reported optimized protocols that ensure high yields and purity levels, which are critical for its use in sensitive applications. The compound's synthesis typically involves the oxidation of TEMPO derivatives under controlled conditions, followed by purification steps such as chromatography and recrystallization.
In terms of applications, 4-Hydroxy-TEMPO Benzoate has found significant utility in the field of polymer science. Its role as a free radical initiator has been pivotal in developing advanced polymer materials with tailored properties. Recent studies have highlighted its ability to initiate controlled radical polymerization (CRP) processes, leading to the production of polymers with precise molecular weights and architectures. This has opened new avenues for applications in drug delivery systems, electronic materials, and advanced composites.
Beyond polymer science, CAS No 3225-26-1 has also been explored in the context of redox chemistry and energy storage systems. Its ability to mediate electron transfer processes makes it a promising candidate for use in batteries and supercapacitors. Researchers have reported enhanced electrochemical performance when incorporating 4-Hydroxy-TEMPO Benzoate into electrode materials, suggesting its potential for next-generation energy storage technologies.
The stability and reactivity of 4-Hydroxy-TEMPO Benzoate have also been studied in detail under various environmental conditions. Recent investigations have revealed that the compound exhibits excellent thermal stability up to 150°C, making it suitable for industrial applications where high temperatures are involved. Additionally, its resistance to photodegradation under UV light exposure has been documented, further enhancing its applicability in outdoor materials and coatings.
In conclusion, CAS No 3225-26-1, or 4-Hydroxy-TEMPO Benzoate, stands as a testament to the ingenuity of modern chemical research. Its unique properties as a free radical species, combined with its versatile applications across multiple disciplines, position it as a key compound in contemporary scientific innovation. As research continues to uncover new potentials for this compound, its role in advancing technology and industry is expected to grow significantly.
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