Cas no 3225-26-1 (4-Hydroxy-TEMPO Benzoate, Free Radical)

4-Hydroxy-TEMPO Benzoate is a stable nitroxide free radical derivative, combining the properties of the TEMPO (2,2,6,6-tetramethylpiperidin-1-oxyl) framework with a benzoate functional group. This compound is widely utilized as a radical scavenger, polymerization inhibitor, and oxidation catalyst due to its persistent radical nature. The benzoate moiety enhances solubility in organic matrices, making it suitable for applications in polymer stabilization, organic synthesis, and materials science. Its ability to quench reactive oxygen species (ROS) and inhibit uncontrolled radical reactions underscores its utility in both industrial and research settings. The compound’s stability and reactivity balance make it a valuable tool for studying and controlling free radical processes.
4-Hydroxy-TEMPO Benzoate, Free Radical structure
3225-26-1 structure
Product Name:4-Hydroxy-TEMPO Benzoate, Free Radical
CAS No:3225-26-1
MF:C16H22NO3
MW:276.350784778595
MDL:MFCD00075563
CID:295139
PubChem ID:24863101
Update Time:2025-10-23

4-Hydroxy-TEMPO Benzoate, Free Radical Chemical and Physical Properties

Names and Identifiers

    • 1-Piperidinyloxy,4-(benzoyloxy)-2,2,6,6-tetramethyl-
    • 4-Hydroxy-2,2,6,6-tetramethylpiperidine 1-Oxyl Benzoate Free Radical[Catalyst for Oxidation]
    • (1-λ<sup>1</sup>-oxidanyl-2,2,6,6-tetramethylpiperidin-4-yl) benzoate
    • 1-oxyl-2,2,6,6-tetramethlpiperidin-4-yl benzoate
    • 4-Benzoyloxy-2,2,6,6-tetramethylpiperidine 1-Oxyl Free Radical
    • 4-benzoyloxy-2,2,6,6-tetramethylpiperidine-1-oxy
    • 4-benzoyloxy-2,2,6,6-tetramethylpiperidine-1-oxyl
    • 4-benzoyloxy-2,6-tetramethylpiperidine-N-oxyl
    • 4-Benzoyloxy-TEMPO
    • 4-Benzoyloxy-TEMPO Free Radical
    • 4-Hydroxy-2,2,6,6-tetramethylpiperidine 1-oxyl benzoate
    • 4-Hydroxy-TEMPO benzoate,free radical
    • 4-Hydroxy-TEMPO-benzoate
    • 4-PhCO2-TEMPO
    • 4-Hydroxy-TEMPO Benzoate Free Radical
    • [4-(Benzoyloxy)-2,2,6,6-tetramethyl-1-piperidinyl]oxidanyl
    • CHEBI:180676
    • 4-Hydroxy-TEMPO benzoate
    • AKOS015889094
    • 4-Benzoyloxy-2,2,6,6-tetramethylpiperidine 1-Oxyl
    • DTXSID20385861
    • H0878
    • MFCD00075563
    • SR-01000209976
    • 4-Hydroxy-TEMPO-benzoat
    • 4-Benzoyloxy-2,2,6,6-tetramethylpiperidinyloxyl
    • 2,2,6,6-Tetramethyl-4-(benzoyloxy)piperidine-1-oxyl
    • FT-0618752
    • B-0840
    • 4-Hydroxy-TEMPO benzoate, free radical, 97%
    • SR-01000209976-1
    • 3225-26-1
    • 4-HYDROXY-TEMPO BENZOATE, FREE RADICAL
    • 4-Benzoyloxy-2,2,6,6-tetramethylpiperidinyloxy, free radical~4-Hydroxy-TEMPO benzoate, free radical
    • 4-Benzyloxy-TEMPO,freeradical
    • 4-Hydroxy-TEMPO Benzoate, Free Radical
    • MDL: MFCD00075563
    • Inchi: 1S/C16H22NO3/c1-15(2)10-13(11-16(3,4)17(15)19)20-14(18)12-8-6-5-7-9-12/h5-9,13H,10-11H2,1-4H3
    • InChI Key: MJEDTBDGYVATPI-UHFFFAOYSA-N
    • SMILES: O(C(C1C=CC=CC=1)=O)C1CC(C)(C)N(C(C)(C)C1)[O] |^1:19|
    • BRN: 1431263

Computed Properties

  • Exact Mass: 276.16000
  • Monoisotopic Mass: 276.16
  • Isotope Atom Count: 0
  • Hydrogen Bond Donor Count: 0
  • Hydrogen Bond Acceptor Count: 2
  • Heavy Atom Count: 20
  • Rotatable Bond Count: 3
  • Complexity: 341
  • Covalently-Bonded Unit Count: 1
  • Defined Atom Stereocenter Count: 0
  • Undefined Atom Stereocenter Count : 0
  • Defined Bond Stereocenter Count: 0
  • Undefined Bond Stereocenter Count: 0
  • Surface Charge: 0
  • Tautomer Count: nothing
  • XLogP3: 3.1
  • Topological Polar Surface Area: 30.5A^2

Experimental Properties

  • Color/Form: Not available
  • Density: 1.1±0.1 g/cm3
  • Melting Point: 99-101?°C (lit.)
  • Boiling Point: 376.8±31.0 °C at 760 mmHg
  • Flash Point: 181.7±24.8 °C
  • Stability/Shelf Life: Stable. Incompatible with strong oxidizing agents.
  • PSA: 29.54000
  • LogP: 3.14840
  • Solubility: Not available
  • Vapor Pressure: 0.0±0.9 mmHg at 25°C

4-Hydroxy-TEMPO Benzoate, Free Radical Security Information

4-Hydroxy-TEMPO Benzoate, Free Radical Customs Data

  • HS CODE:29329990

4-Hydroxy-TEMPO Benzoate, Free Radical Pricemore >>

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4-Hydroxy-TEMPO Benzoate, Free Radical Suppliers

Amadis Chemical Company Limited
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(CAS:3225-26-1)4-Hydroxy-TEMPO Benzoate, Free Radical
Order Number:A1201143
Stock Status:in Stock
Quantity:25g
Purity:99%
Pricing Information Last Updated:Friday, 30 August 2024 02:44
Price ($):501.0

4-Hydroxy-TEMPO Benzoate, Free Radical Related Literature

Additional information on 4-Hydroxy-TEMPO Benzoate, Free Radical

4-Hydroxy-TEMPO Benzoate, Free Radical: A Comprehensive Overview

The compound with CAS No 3225-26-1, commonly referred to as 4-Hydroxy-TEMPO Benzoate, is a highly specialized chemical entity that has garnered significant attention in the fields of organic chemistry, materials science, and pharmaceutical research. This compound is notable for its unique structure and functional properties, particularly its role as a free radical species. In this article, we delve into the latest research findings and applications of 4-Hydroxy-TEMPO Benzoate, highlighting its significance in modern scientific advancements.

4-Hydroxy-TEMPO Benzoate is a derivative of TEMPO (tert-butyl hydroperoxide), a well-known oxidizing agent. The introduction of the hydroxyl group at the fourth position of the benzoate ring imparts unique electronic and steric properties to the molecule. Recent studies have demonstrated that this modification enhances the compound's stability and reactivity, making it an ideal candidate for various applications in radical chemistry. The ability of 4-Hydroxy-TEMPO Benzoate to act as a free radical has been extensively explored in the context of polymerization reactions and redox processes.

The synthesis of CAS No 3225-26-1 involves a multi-step process that combines traditional organic synthesis techniques with modern catalytic methods. Researchers have reported optimized protocols that ensure high yields and purity levels, which are critical for its use in sensitive applications. The compound's synthesis typically involves the oxidation of TEMPO derivatives under controlled conditions, followed by purification steps such as chromatography and recrystallization.

In terms of applications, 4-Hydroxy-TEMPO Benzoate has found significant utility in the field of polymer science. Its role as a free radical initiator has been pivotal in developing advanced polymer materials with tailored properties. Recent studies have highlighted its ability to initiate controlled radical polymerization (CRP) processes, leading to the production of polymers with precise molecular weights and architectures. This has opened new avenues for applications in drug delivery systems, electronic materials, and advanced composites.

Beyond polymer science, CAS No 3225-26-1 has also been explored in the context of redox chemistry and energy storage systems. Its ability to mediate electron transfer processes makes it a promising candidate for use in batteries and supercapacitors. Researchers have reported enhanced electrochemical performance when incorporating 4-Hydroxy-TEMPO Benzoate into electrode materials, suggesting its potential for next-generation energy storage technologies.

The stability and reactivity of 4-Hydroxy-TEMPO Benzoate have also been studied in detail under various environmental conditions. Recent investigations have revealed that the compound exhibits excellent thermal stability up to 150°C, making it suitable for industrial applications where high temperatures are involved. Additionally, its resistance to photodegradation under UV light exposure has been documented, further enhancing its applicability in outdoor materials and coatings.

In conclusion, CAS No 3225-26-1, or 4-Hydroxy-TEMPO Benzoate, stands as a testament to the ingenuity of modern chemical research. Its unique properties as a free radical species, combined with its versatile applications across multiple disciplines, position it as a key compound in contemporary scientific innovation. As research continues to uncover new potentials for this compound, its role in advancing technology and industry is expected to grow significantly.

Recommended suppliers
Amadis Chemical Company Limited
(CAS:3225-26-1)4-Hydroxy-TEMPO Benzoate, Free Radical
A1201143
Purity:99%
Quantity:25g
Price ($):501.0
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