Cas no 24973-59-9 (2,4,6-Tri-tert-Butylnitrosobenzene)
2,4,6-Tri-tert-Butylnitrosobenzene is a sterically hindered nitrosobenzene derivative characterized by its three tert-butyl substituents. This compound is notable for its stability due to the bulky tert-butyl groups, which shield the reactive nitroso functional group from decomposition or unwanted reactions. It is commonly employed as a spin trap in electron paramagnetic resonance (EPR) spectroscopy for detecting and studying short-lived free radicals. The tert-butyl groups enhance solubility in organic solvents, facilitating its use in various reaction media. Its robust structure also makes it suitable for mechanistic studies in radical chemistry. The compound’s high purity and predictable reactivity are advantageous for precise experimental applications.
24973-59-9 structure
Product Name:2,4,6-Tri-tert-Butylnitrosobenzene
CAS No:24973-59-9
MF:C18H29NO
MW:275.428965330124
CID:269532
PubChem ID:87577293
Update Time:2025-05-28
2,4,6-Tri-tert-Butylnitrosobenzene Chemical and Physical Properties
Names and Identifiers
-
- 1,3,5-Tri-tert-butyl-2-nitrosobenzene
- 2,4,6-Tri-tert-butylnitrosobenzene
- 1,3,5-tritert-butyl-2-nitrosobenzene
- 2,4,6-TRI-TERT-BUTYLNITROSOBENZENE [SPIN TRAPPING REAGENT]
- Benzene,1,3,5-tris(1,1-dimethylethyl)-2-nitroso-
- 2,4,6-tri-t-butylnitrosobenzene
- 2,4,6-tri-tert-butyl-1-nitrosobenzene
- 2,4,6-Tri-tert-butylnitrosobenzene,2-Nitroso-1,3,5-tri-tert-butylbenzene,TTBNB
- TTBNB
- Benzene,1,3,5-tri-tert-butyl-2-nitroso- (8CI)
- 1-Nitroso-2,4,6-tri-t-butylbenzene
- NSC 677542
- 2,4,6-Tri-t-butyl-nitrosobenzene
- NSC677542
- 1,3,5-Tri(tert-butyl)-2-nitrosobenzene
- Benzene, 1,3,5-tris(1,1-dimethylethyl)-2-nitroso-
- 2-Nitroso-1,3,5-tri-tert-butylbenzene
- OSICDPWAPKXXHT-UH
- 1,3,5-Tri-tert-butyl-2-nitrosobenzene, for ESR-spectroscopy, >98.0% (HPLC)
- AKOS004120290
- T72161
- EINECS 246-553-3
- SZX3GP4GT9
- NS00027779
- J-640237
- FT-0745688
- OSICDPWAPKXXHT-UHFFFAOYSA-N
- T1534
- NSC-677542
- ZAA97359
- Nitrosobenzene, 2,4,6-tri-tert-butyl-
- AS-68087
- 1,3,5-tritert-butyl-2-nitroso-benzene
- 1, 3, 5-tritert-butyl-2-nitrosobenzene
- DTXSID40179688
- UNII-SZX3GP4GT9
- 1,3,5-TRIS(1,1-DIMETHYLETHYL)-2-NITROSOBENZENE
- 24973-59-9
- SCHEMBL104121
- 2,4,6-Tri-tert-Butylnitrosobenzene
-
- MDL： MFCD00008817
- Inchi： 1S/C18H29NO/c1-16(2,3)12-10-13(17(4,5)6)15(19-20)14(11-12)18(7,8)9/h10-11H,1-9H3
- InChI Key： OSICDPWAPKXXHT-UHFFFAOYSA-N
- SMILES： O=NC1C(=CC(=CC=1C(C)(C)C)C(C)(C)C)C(C)(C)C
Computed Properties
- Exact Mass: 275.22500
- Monoisotopic Mass: 275.224915
- Isotope Atom Count: 0
- Hydrogen Bond Donor Count: 0
- Hydrogen Bond Acceptor Count: 2
- Heavy Atom Count: 20
- Rotatable Bond Count: 3
- Complexity: 316
- Covalently-Bonded Unit Count: 1
- Defined Atom Stereocenter Count: 0
- Undefined Atom Stereocenter Count : 0
- Defined Bond Stereocenter Count: 0
- Undefined Bond Stereocenter Count: 0
- Surface Charge: 0
- Tautomer Count: nothing
- XLogP3: 6.3
- Topological Polar Surface Area: 29.4
Experimental Properties
- Color/Form: Not determined
- Density: 0.9809 (rough estimate)
- Melting Point: 168°C(lit.)
- Boiling Point: 418.37°C (rough estimate)
- Flash Point: 130.2°C
- Refractive Index: 1.5000 (estimate)
- PSA: 29.43000
- LogP: 5.97700
- Solubility: Not determined
2,4,6-Tri-tert-Butylnitrosobenzene Security Information
- WGK Germany：3
- Safety Instruction： 24/25
- Storage Condition：0-10°C
2,4,6-Tri-tert-Butylnitrosobenzene Customs Data
- HS CODE：2904209090
- Customs Data：
China Customs Code:
2904209090Overview:
2904209090 Other derivatives containing only nitro or nitroso groups.Regulatory conditions:nothing.VAT:17.0%.Tax refund rate:9.0%.MFN tariff:5.5%.general tariff:30.0%
Declaration elements:
Product Name, component content, use to
Summary:
2904209090 derivatives containing only nitro or only nitroso groups.Supervision conditions:None.VAT:17.0%.Tax rebate rate:9.0%.MFN tariff:5.5%.General tariff:30.0%
2,4,6-Tri-tert-Butylnitrosobenzene Pricemore >>
| Related Categories | No. | Product Name | Cas No. | Purity | Specification | Price | update time | Inquiry |
|---|---|---|---|---|---|---|---|---|
| TI XI AI ( SHANG HAI ) HUA CHENG GONG YE FA ZHAN Co., Ltd. | T1534-1G |
2,4,6-Tri-tert-butylnitrosobenzene |
24973-59-9 | >98.0%(GC) | 1g |
￥2040.00 | 2024-04-17 | |
| SHANG HAI A LA DING SHENG HUA KE JI GU FEN Co., Ltd. | T161849-1G |
2,4,6-Tri-tert-Butylnitrosobenzene |
24973-59-9 | >98.0%(GC) | 1g |
￥2040.90 | 2023-08-31 | |
| SHANG HAI A LA DING SHENG HUA KE JI GU FEN Co., Ltd. | T161849-100MG |
2,4,6-Tri-tert-Butylnitrosobenzene |
24973-59-9 | >98.0%(GC) | 100mg |
￥409.90 | 2023-08-31 | |
| SHANG HAI MAI KE LIN SHENG HUA Technology Co., Ltd. | T867928-100mg |
2,4,6-Tri-tert-butylnitrosobenzene |
24973-59-9 | ≥98% | 100mg |
￥452.00 | 2022-09-28 | |
| SHANG HAI JI ZHI SHENG HUA Technology Co., Ltd. | X72825-100mg |
1,3,5-tritert-butyl-2-nitrosobenzene |
24973-59-9 | ≥98% | 100mg |
￥368.0 | 2023-09-05 | |
| TRC | T886608-1mg |
2,4,6-Tri-tert-butylnitrosobenzene |
24973-59-9 | 1mg |
45.00 | 2021-07-16 | ||
| TRC | T886608-2mg |
2,4,6-Tri-tert-butylnitrosobenzene |
24973-59-9 | 2mg |
60.00 | 2021-07-16 | ||
| TRC | T886608-10mg |
2,4,6-Tri-tert-butylnitrosobenzene |
24973-59-9 | 10mg |
75.00 | 2021-07-16 | ||
| TI XI AI ( SHANG HAI ) HUA CHENG GONG YE FA ZHAN Co., Ltd. | T1534-100MG |
2,4,6-Tri-tert-butylnitrosobenzene |
24973-59-9 | >98.0%(GC) | 100mg |
￥390.00 | 2024-04-17 | |
| TRC | T886608-100mg |
2,4,6-Tri-tert-butylnitrosobenzene |
24973-59-9 | 100mg |
$345.00 | 2023-05-17 |
2,4,6-Tri-tert-Butylnitrosobenzene Related Literature
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1. Spin trapping by use of nitroso-compounds. Part V. 2,4,6-Tri-t-butylnitrosobenzene: a new type of spin-trapping reagentShigeru Terabe,Ryusei Konaka J. Chem. Soc. Perkin Trans. 2 1973 369
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2. The EPR spectra of thiyl radical spin adducts produced by photolysis of disulfides in the presence of 2,4,6-tri-tert-butylnitrosobenzene and 5,5-dimethyl-1-pyrroline N-oxideBrynmor Mile,Christopher C. Rowlands,Philip D. Sillman,Melanie Fildes J. Chem. Soc. Perkin Trans. 2 1992 1431
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3. An EPR spin-trap study of the radicals present during the thermolysis of some novel monoperoxycarbonates and peroxydicarbonatesPierre G. Mekarbane,Brian J. Tabner J. Chem. Soc. Perkin Trans. 2 2000 1465
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Jun Zhou,Zhengyu Zhao,Bingyao Jiang,Katsuhiro Yamamoto,Yuji Sumii,Norio Shibata Chem. Sci. 2023 14 4248
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Jun Zhou,Zhengyu Zhao,Bingyao Jiang,Katsuhiro Yamamoto,Yuji Sumii,Norio Shibata Chem. Sci. 2023 14 4248
24973-59-9 (2,4,6-Tri-tert-Butylnitrosobenzene) Related Products
- 25798-69-0(Benzene, 1,4-bis(1,1-dimethylethyl)-2-nitroso-)
- 275795-16-9(1,1'-Biphenyl,3-(1,1-dimethylethyl)-4-nitroso-)
- 93720-37-7(Benzene, 2,4-bis(1,1-dimethylethyl)-1-nitro-)
- 21460-40-2(Benzene, 1-methyl-4-(1-methylethyl)-2,5-dinitroso-)
- 20444-30-8(Benzene, 1,5-bis(1,1-dimethylethyl)-3-methyl-2-nitro-)
- 1886-57-3(1-tert-Butyl-2-nitrobenzene)
- 106273-86-3(1-tert-butyl-3,5-dimethyl-2-nitrobenzene)
- 153071-87-5(Benzene, 1,4-dinitroso-2-(phenylmethyl)-)
- 16433-80-0(Benzene, 1-ethyl-2-nitroso-)
- 4074-25-3(2,4,6-Tri-tert-butylnitrobenzene)
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