Cas no 246231-77-6 ((S)-1-[(R)-2-(dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine)
(S)-1-[(R)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine is a chiral ferrocenyl phosphine ligand widely used in asymmetric catalysis. Its rigid ferrocene backbone and sterically demanding dicyclohexylphosphino groups enhance enantioselectivity in transition-metal-catalyzed reactions, such as hydrogenations and cross-couplings. The (S,R) configuration ensures high stereocontrol, making it valuable for synthesizing optically active compounds.
![(S)-1-[(R)-2-(dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine structure](https://ossimg.kuujia.com/scimg/246500/246231-77-6x500.png)
246231-77-6 structure
Product Name:(S)-1-[(R)-2-(dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine
(S)-1-[(R)-2-(dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine Chemical and Physical Properties
Names and Identifiers
-
- Ferrocene,1-(dicyclohexylphosphino)-2-[(1S)-1-(dicyclohexylphosphino)ethyl]-, (1S)-
- cyclopenta-1,3-diene,dicyclohexyl-[(1S)-1-(2-dicyclohexylphosphanylcyclopenta-2,4-dien-1-yl)ethyl]phosphane,iron(2+)
- (S)-1-[(RP)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine
- Josiphos SL-J003-2
- 1-[2-(dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine
- (s,s)-1-dicyclohexylphosphino-2-[1-(dicyclohexylphosphino)ethyl]ferrocene (acc to cas)
- Josiphos SL-J003-2, (1S)-1-(Dicyclohexylphosphino)-2-[(1S)-1-(dicyclohexylphosphino)ethyl]ferrocene (acc to CAS)
- (1S)-1-(Dicyclohexylphosphino)-2-[(1S)-1-(dicyclohexylphosphino)ethyl]ferrocene(acc to CAS)
- (1S)-1-(Dicyclohexylphosphino)-2-[(1S)-1-(dicyclohexylphosphino)ethyl]ferrocene
- (S)-1-[(S)-2-(Dicyclohexylphosphino)-ferrocenyl]ethyldicyclohexylphosphine
- Ferrocene, 1-(dicyclohexylphosphino)-2-[(1S)-1-(dicyclohexylphosphino)ethyl]-, (1S)-
- (S)-1-[(Rp)-2-(Dicyclohexylphosphino)ferrocenyl]ethyl dicyclohexylphosphine
- (S)-1-[(R)-2-(dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine
-
- MDL： MFCD00800279
- Inchi： 1S/C31H51P2.C5H5.Fe/c1-25(32(26-15-6-2-7-16-26)27-17-8-3-9-18-27)30-23-14-24-31(30)33(28-19-10-4-11-20-28)29-21-12-5-13-22-29;1-2-4-5-3-1;/h14,23-29H,2-13,15-22H2,1H3;1-5H;/q2*-1;+2/t25-;;/m0../s1
- InChI Key： LHVQVTRNQNYQQT-WLOLSGMKSA-N
- SMILES： [Fe+2].P([C@@H](C)[C-]1C=CC=C1P(C1CCCCC1)C1CCCCC1)(C1CCCCC1)C1CCCCC1.[CH-]1C=CC=C1
Experimental Properties
- PSA: 27.18000
- LogP: 12.01190
- Specific Rotation: +139° ±4° (c 0.5, CHCl3)
(S)-1-[(R)-2-(dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine Security Information
- Hazardous Material transportation number：NONH for all modes of transport
- WGK Germany：3
- FLUKA BRAND F CODES：10
- Storage Condition：under inert gas (nitrogen or Argon) at 2-8°C
(S)-1-[(R)-2-(dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine Pricemore >>
| Related Categories | No. | Product Name | Cas No. | Purity | Specification | Price | update time | Inquiry |
|---|---|---|---|---|---|---|---|---|
| SU ZHOU XIN JIA YUAN HUA XUE Technology Co., Ltd. | 600419-2g |
(S)-1-[(R)-2-(dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine |
246231-77-6 | 97% | 2g |
￥2000.0 | 2024-07-19 | |
| SU ZHOU XIN JIA YUAN HUA XUE Technology Co., Ltd. | 600419-100mg |
(S)-1-[(R)-2-(dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine |
246231-77-6 | 97% | 100mg |
￥150.0 | 2024-07-19 | |
| SU ZHOU XIN JIA YUAN HUA XUE Technology Co., Ltd. | 600419-500mg |
(S)-1-[(R)-2-(dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine |
246231-77-6 | 97% | 500mg |
￥580.0 | 2024-07-19 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | 26-1001-500mg |
(S)-1-[(R)-2-(dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine |
246231-77-6 | min.97% | 500mg |
4189.0CNY | 2021-07-10 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | 26-1001-10g |
(S)-1-[(R)-2-(dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine |
246231-77-6 | min.97% | 10g |
48934.0CNY | 2021-07-10 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | 26-1001-100mg |
(S)-1-[(R)-2-(dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine |
246231-77-6 | min.97% | 100mg |
1197.0CNY | 2021-07-10 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | 26-1001-2g |
(S)-1-[(R)-2-(dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine |
246231-77-6 | min.97% | 2g |
11514.0CNY | 2021-07-10 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | B-HC972-50mg |
(S)-(+)-1-[(R)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine,min.97% |
246231-77-6 | 98% 99%ee | 50mg |
￥189.0 | 2022-06-09 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | B-HC972-200mg |
(S)-(+)-1-[(R)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine,min.97% |
246231-77-6 | 98% 99%ee | 200mg |
￥533.0 | 2022-06-09 | |
| ChemScence | CS-0097605-100mg |
(1S)-1-(Dicyclohexylphosphino)-2-[(1S)-1-(dicyclohexylphosphino)ethyl]ferrocene |
246231-77-6 | ≥97.0% | 100mg |
$48.0 | 2022-04-27 |
(S)-1-[(R)-2-(dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine Related Literature
-
J. M. Granadino-Roldán,M. Fernández-Gómez,A. Navarro,T. Pe?a Ruiz,U. A. Jayasooriya Phys. Chem. Chem. Phys., 2004,6, 1133-1143
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Karl Crowley,Eimer O'Malley,Aoife Morrin,Malcolm R. Smyth,Anthony J. Killard Analyst, 2008,133, 391-399
-
Jianyao Huang,Dong Gao,Zhihui Chen,Weifeng Zhang Polym. Chem., 2021,12, 2471-2480
-
Haitao Li,Yu Pan,Zhizhi Wang,Shan Chen,Ruixin Guo,Jianqiu Chen RSC Adv., 2015,5, 100775-100782
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