• 1. 238. Mechanism of substitution at a saturated carbon atom. Part LVI. Kinetics of the reaction of triphenylmethyl chloride with methyl alcohol in benzene
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• 2. 236. Mechanism of substitution at a saturated carbon atom. Part LIV. Kinetics of chlorine exchange between triphenylmethyl chloride and tetra-n-butylammonium chloride in benzene
  E. D. Hughes,C. K. Ingold,S. F. Mok,S. Patai,Y. Pocker J. Chem. Soc. 1957 1220
• 3. The electrochemical formation and properties of bilayers composed of polypyrrole and C60Pd films
  Monika Wysocka,Krzysztof Winkler,Alan L. Balch J. Mater. Chem. 2004 14 1036
• 4. Redox-active films formed by electrochemical reduction of solutions of C60 and platinum complexes
  Akari Hayashi,Ana de Bettencourt-Dias,Krzysztof Winkler,Alan L. Balch J. Mater. Chem. 2002 12 2116
• 5. Charge transfer processes in bilayers and co-polymers composed of C60Pd and 2′-ferrocenylpyrrolidino-[3′,4′;1,2]C60Pd two-component polymers
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• Solvents and Organic Chemicals Organic Compounds Organic oxygen compounds Organic oxoanionic compounds Organic perchlorates
• Catalysts and Inorganic Chemicals Inorganic Compounds Salt

Tetrabutylammonium Perchlorate (CAS No. 1923-70-2): An Overview of Its Properties, Applications, and Recent Research

Tetrabutylammonium perchlorate (TBAP), with the CAS number 1923-70-2, is a widely used compound in various scientific and industrial applications. This organic salt is composed of a tetrabutylammonium cation and a perchlorate anion, making it highly versatile in both laboratory and commercial settings. TBAP is known for its excellent solubility in polar solvents and its ability to form stable complexes with a variety of organic and inorganic compounds.

The chemical structure of Tetrabutylammonium perchlorate consists of a large, lipophilic tetrabutylammonium cation (C₁₆H₃₆N⁺) and a highly oxidizing perchlorate anion (ClO₄^-). This unique combination of properties makes TBAP particularly useful in various chemical reactions, including phase transfer catalysis, ion-pair chromatography, and as a supporting electrolyte in electrochemical studies.

In the realm of phase transfer catalysis, TBAP plays a crucial role by facilitating the transfer of ionic species from an aqueous phase to an organic phase. This process is essential in many synthetic reactions, such as nucleophilic substitutions and condensation reactions. The ability of TBAP to bridge the gap between these two phases enhances reaction efficiency and selectivity, making it an indispensable tool in organic synthesis.

Recent research has also highlighted the potential of Tetrabutylammonium perchlorate in the development of new materials. For instance, studies have shown that TBAP can be used as a template for the synthesis of mesoporous silica nanoparticles. These nanoparticles have applications in drug delivery systems, catalysis, and environmental remediation. The use of TBAP as a template allows for precise control over the size and shape of the nanoparticles, which is critical for optimizing their performance in various applications.

In addition to its use in material science, TBAP has found applications in analytical chemistry. Its ability to form stable ion pairs with various analytes makes it useful in ion-pair chromatography. This technique is widely used for the separation and analysis of ionic compounds that are difficult to separate using conventional methods. Recent advancements in this area have led to the development of more sensitive and accurate analytical methods for detecting trace amounts of ionic species in complex matrices.

The electrochemical properties of Tetrabutylammonium perchlorate have also been extensively studied. As a supporting electrolyte, TBAP helps to maintain a stable potential during electrochemical reactions by providing a source of mobile ions. This property is particularly important in cyclic voltammetry and other electroanalytical techniques. Recent research has focused on optimizing the concentration and composition of TBAP solutions to enhance the sensitivity and reproducibility of these techniques.

Beyond its technical applications, Tetrabutylammonium perchlorate has been explored for its potential biological activities. Some studies have investigated its effects on cellular processes, including its ability to modulate ion channels and transporters. While more research is needed to fully understand these biological effects, preliminary findings suggest that TBAP could have therapeutic potential in certain conditions.

In conclusion, Tetrabutylammonium perchlorate (CAS No. 1923-70-2) is a versatile compound with a wide range of applications in chemistry, materials science, analytical chemistry, and potentially biology. Its unique properties make it an essential tool in many scientific disciplines, driving innovation and advancing our understanding of complex systems. As research continues to uncover new uses for this compound, its importance is likely to grow even further.

• 139653-47-7(1-Tetradecanaminium, N,N,N-tritetradecyl-, perchlorate)
• 62207-11-8(Tetrakis(decyl)ammonium perchlorate)
• 69722-80-1(1-Nonanaminium, N,N,N-trinonyl-, perchlorate)
• 99051-44-2(1-Propanaminium, N,N,N-triethyl-, perchlorate)
• 139653-36-4(1-Octadecanaminium, N-methyl-N,N-dioctadecyl-, perchlorate)
• 139995-80-5(1-Dodecanaminium, N,N,N-tripropyl-, perchlorate)
• 29711-00-0(1-Dodecanaminium, N,N-didodecyl-N-methyl-, perchlorate)
• 869093-57-2(1-octadecanamine, N-octadecyl-, perchlorate (1:1))
• 869093-50-5(1-dodecanamine, N-dodecyl-, perchlorate (1:1))
• 62120-45-0(Tetradodecylammonium perchlorate)