Cas no 18401-43-9 (5-(Triethoxysilyl)-2-norbornene (mixture of isomers))
5-(Triethoxysilyl)-2-norbornene (mixture of isomers) Chemical and Physical Properties
Names and Identifiers
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- Bicyclo[2.2.1]hept-2-ene,5-(triethoxysilyl)-
- [Bicyclo[2.2.1]hept-5-en-2-yl]triethoxysilane (mixture of isomers)
- (BICYCLO[2.2.1]HEPT-5-EN-2-YL)TRI- ETHOXYSILANE TECHN. MIXTURES OF ISOMERS
- 5-bicyclo[2.2.1]hept-2-enyl(triethoxy)silane
- [Bicyclo[2.2.1]hept-5-en-2-yl]triethoxysilane
- 5-(BICYCLOHEPTENYL)TRIETHOXYSILANE
- 5-(Triethoxysilyl)-2-norbornene
- 5-(Triethoxysilyl)bicyclo[2.2.1]hept-2-ene
- 5-NORBORNEN-2-YLTRIETHOXYSILANE
- 6-Triethoxysilyl-2-bicyclo<2.2.1>hepten
- Triaethoxy-norborn-5-en-2-yl-silan
- triethoxy-norborn-5-en-2-yl-silane
- 5-(Triethoxysilyl)bicyclo[2.2.1]hept-2-ene (mixture of isomers)
- 5-(Triethoxysilyl)-2-norbornene (mixture of isomers)
- 5-Triethoxysilylbicyclo[2.2.1]hept-2-ene
- bicyclo[2.2.1]hept-5-en-2-yltriethoxy-silan
- Silane,bicyclo[2.2.1]hept-5-en-2-yltriethoxy-
- LS 5080
- SIB 0992
- 5-(Triethoxysilyl)norborna-2-ene
- (Norborna-5-ene-2-yl)triethoxysilane
- 6-Triethoxysilylbicyclo[2.2.1]hept-2-ene
- 5-(TRITHOXYSILYL)BICYCLO[2.2.1]HEPT-2-ENE
- 5-(Triethoxysilyl)bicyclo[2.2.1]hepta-2-ene
- bicyclo[2.2.1]hept-5-en-2-yltriethoxysilane
- Silane, bicyclo(2.2.1)hept-5-en-2-yltriethoxy-
- Silane, bicyclo[2.2.1]hept-5-en-2-yltriethoxy-
- 5-Triethoxysilylbicyclo(2.2.1)hept-2-ene
- Bicyclo(2.2.1)hept-5-en-2-yltriethoxysilane
- Bicyclo[2.2.1]hept-2-ene, 5-(triethoxysilyl)-
- Bicyclo(2.2.1)hept-2-ene, 5-(triethoxysilyl)-
- AKOS024319286
- SY057895
- MFCD00167591
- 2-bicyclo[2.2.1]hept-5-enyl(triethoxy)silane
- Bicyclo[2.2.1]hept-5-en-2-yl(triethoxy)silane #
- DTXSID60885032
- 5-(triethoxysilyl)norbornene
- Bicycloheptenyltriethoxysilane
- CS-0151948
- NS00052907
- 18401-43-9
- EINECS 242-278-8
- HHKDWDAAEFGBAC-UHFFFAOYSA-N
- 5-triethoxysilyl-2-norbornene
- FT-0619691
- B3214
- SCHEMBL122625
- (5-BICYCLO[2.2.1]HEPT-2-ENYL)TRIETHOXYSILANE, tech, endo/exo isomers
-
- MDL: MFCD00167591
- Inchi: 1S/C13H24O3Si/c1-4-14-17(15-5-2,16-6-3)13-10-11-7-8-12(13)9-11/h7-8,11-13H,4-6,9-10H2,1-3H3
- InChI Key: HHKDWDAAEFGBAC-UHFFFAOYSA-N
- SMILES: [Si](C1CC2C=CC1C2)(OCC)(OCC)OCC
Computed Properties
- Exact Mass: 256.14900
- Monoisotopic Mass: 256.149
- Isotope Atom Count: 0
- Hydrogen Bond Donor Count: 0
- Hydrogen Bond Acceptor Count: 3
- Heavy Atom Count: 17
- Rotatable Bond Count: 7
- Complexity: 263
- Covalently-Bonded Unit Count: 1
- Defined Atom Stereocenter Count: 0
- Undefined Atom Stereocenter Count : 3
- Defined Bond Stereocenter Count: 0
- Undefined Bond Stereocenter Count: 0
- Surface Charge: 0
- Tautomer Count: nothing
- XLogP3: nothing
- Topological Polar Surface Area: 27.7
Experimental Properties
- Color/Form: Uncertain
- Density: 0.960 g/cm3
- Boiling Point: 104°C/7mmHg(lit.)
- Flash Point: 128.0±29.3 oC,
- Refractive Index: 1.4486
- Solubility: Almost insoluble (0.031 g/l) (25 o C),
- PSA: 27.69000
- LogP: 3.00100
- Solubility: Uncertain
5-(Triethoxysilyl)-2-norbornene (mixture of isomers) Security Information
-
Symbol:
- Prompt:warning
- Signal Word:warning
- Hazard Statement: H315-H319
- Warning Statement: P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313
- WGK Germany:3
- Hazard Category Code: 36/37/38
- Safety Instruction: S26; S36
- FLUKA BRAND F CODES:21
-
Hazardous Material Identification:
- TSCA:Yes
- Risk Phrases:R36/37/38
- Storage Condition:Store at 4°C,-4At ℃Store…Better
5-(Triethoxysilyl)-2-norbornene (mixture of isomers) Customs Data
- HS CODE:2931900090
- Customs Data:
China Customs Code:
2931900090Overview:
2931900090. Other organic-Inorganic compound. VAT:17.0%. Tax refund rate:13.0%. Regulatory conditions:AB(Customs clearance form for Inbound Goods,Customs clearance form for outbound goods). MFN tariff:6.5%. general tariff:30.0%
Summary:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%
5-(Triethoxysilyl)-2-norbornene (mixture of isomers) Pricemore >>
| Related Categories | No. | Product Name | Cas No. | Purity | Specification | Price | update time | Inquiry |
|---|---|---|---|---|---|---|---|---|
| Fluorochem | S01175-5g |
5-(Bicycloheptenyl)triethoxysilane |
18401-43-9 | >97.0%(GC) | 5g |
£32.00 | 2022-02-28 | |
| Fluorochem | S01175-10g |
5-(Bicycloheptenyl)triethoxysilane |
18401-43-9 | >97.0%(GC) | 10g |
£59.00 | 2022-02-28 | |
| Fluorochem | S01175-50g |
5-(Bicycloheptenyl)triethoxysilane |
18401-43-9 | >97.0%(GC) | 50g |
£230.00 | 2022-02-28 | |
| TI XI AI ( SHANG HAI ) HUA CHENG GONG YE FA ZHAN Co., Ltd. | B3214-5G |
[Bicyclo[2.2.1]hept-5-en-2-yl]triethoxysilane (mixture of isomers) |
18401-43-9 | >97.0%(GC) | 5g |
¥675.00 | 2023-06-14 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | VH171-1g |
5-(Triethoxysilyl)-2-norbornene (mixture of isomers) |
18401-43-9 | 97.0%(GC) | 1g |
¥317.0 | 2022-06-10 | |
| abcr | AB108971-10 g |
5-(Bicycloheptenyl)triethoxysilane, 97%; . |
18401-43-9 | 97% | 10 g |
€50.70 | 2023-07-20 | |
| abcr | AB108971-50 g |
5-(Bicycloheptenyl)triethoxysilane, 97%; . |
18401-43-9 | 97% | 50 g |
€195.00 | 2023-07-20 | |
| TRC | T797695-10mg |
5-(Triethoxysilyl)-2-norbornene (mixture of isomers) |
18401-43-9 | 10mg |
$ 50.00 | 2022-06-02 | ||
| TRC | T797695-50mg |
5-(Triethoxysilyl)-2-norbornene (mixture of isomers) |
18401-43-9 | 50mg |
$ 65.00 | 2022-06-02 | ||
| TRC | T797695-100mg |
5-(Triethoxysilyl)-2-norbornene (mixture of isomers) |
18401-43-9 | 100mg |
$ 80.00 | 2022-06-02 |
5-(Triethoxysilyl)-2-norbornene (mixture of isomers) Suppliers
5-(Triethoxysilyl)-2-norbornene (mixture of isomers) Related Literature
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Xinhuan Wang,Shuangfei Cai,Cui Qi Analyst, 2017,142, 2500-2506
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Yiding Jiao,Liqun Kang,Jasper Berry-Gair,Kit McColl,Jianwei Li,Haobo Dong,Hao Jiang,Ryan Wang,Furio Corà,Dan J. L. Brett,Ivan P. Parkin J. Mater. Chem. A, 2020,8, 22075-22082
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Marcin Czapla,Jack Simons Phys. Chem. Chem. Phys., 2018,20, 21739-21745
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Hongxia Li,Aikifa Raza,Qiaoyu Ge,Jin-You Lu,TieJun Zhang Soft Matter, 2020,16, 6841-6849
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Guang Xu,Wei Zhang,Ying Zhang,Xiaoxia Zhao,Ping Wen,Di Ma RSC Adv., 2018,8, 19353-19361
Additional information on 5-(Triethoxysilyl)-2-norbornene (mixture of isomers)
5-(Triethoxysilyl)-2-norbornene (mixture of isomers): A Versatile Silane Coupling Agent in Advanced Material Applications
5-(Triethoxysilyl)-2-norbornene (mixture of isomers), identified by its CAS number 18401-43-9, represents a critical silane coupling agent with unique chemical properties and functional versatility. This compound is a mixture of isomers derived from the reaction of 2-norbornene with triethoxysilane, forming a hybrid structure that combines the ring-opening capabilities of norbornene with the surface-reactive functionality of silane groups. Its molecular architecture enables it to act as a bridge between inorganic and organic materials, making it a key component in the development of advanced composites, coatings, and nanomaterials.
Recent advancements in materials science have highlighted the importance of 5-(Triethoxysilyl)-2-norbornene (mixture of isomers) as a multifunctional building block. A 2023 study published in Advanced Functional Materials demonstrated its application in creating self-healing polymer networks through dynamic covalent bonds. The compound's ability to undergo ring-opening polymerization (ROP) at moderate temperatures provides tunable crosslinking densities, which are critical for optimizing mechanical properties in hybrid materials. This functionality has also been leveraged in the synthesis of smart hydrogels for biomedical applications, where controlled swelling and degradation rates are essential.
The chemical structure of 5-(Triethoxysilyl)-2-norbornene (mixture of isomers) features a strained norbornene ring with a triethoxysilane substituent at the 5-position. The norbornene ring, characterized by its high ring strain, undergoes facile ring-opening reactions under mild conditions, while the triethoxysilane group provides hydrolyzable silanol functionalities. This dual functionality allows the compound to act as a coupling agent between inorganic substrates (e.g., silica, alumina) and organic polymers (e.g., epoxy, polyurethane). The resulting hybrid materials exhibit enhanced interfacial adhesion, thermal stability, and chemical resistance, which are crucial for industrial applications.
Recent research has expanded the utility of 5-(Triethoxysilyl)-2-nor, bornene (mixture of isomers) beyond traditional coupling agents. A 2024 study in ACS Applied Materials & Interfaces explored its role in the fabrication of 3D-printable nanocomposites. By incorporating the compound into a polymeric matrix, researchers achieved improved dispersion of functional nanoparticles and enhanced mechanical performance. The silane groups facilitated strong interactions between the polymer matrix and the nanofillers, reducing interfacial voids and improving load transfer efficiency. This application highlights the compound's potential in additive manufacturing technologies for aerospace and automotive industries.
In the field of surface engineering, 5-(Triethoxysilyl)-2-norbornene (mixture of isomers) has been utilized to create functional coatings with tailored surface properties. A 2023 review in Progress in Organic Coatings emphasized its role in the development of superhydrophobic surfaces. The compound's silane groups undergo hydrolysis and condensation reactions to form a silica-like layer, while the norbornene ring provides a flexible backbone that prevents surface cracking. This combination of properties has enabled the creation of coatings with contact angles exceeding 150°, demonstrating its relevance in anti-fouling and self-cleaning applications.
The synthesis of 5-(Triethoxysilyl)-2-norbornene (mixture of isomers) typically involves the reaction of 2-norbornene with chlorotriethoxysilane under controlled conditions. This reaction, which proceeds via a nucleophilic substitution mechanism, yields a mixture of isomers due to the planar geometry of the norbornene ring. The resulting product is purified through column chromatography to separate the isomers, which exhibit slightly different reactivity profiles. This isomer mixture is advantageous in applications requiring broad reactivity, as it can accommodate variations in reaction conditions and substrates.
Recent studies have also explored the environmental impact of 5-(Triethoxysilyl)-2-norbornene (mixture of isomers) in industrial processes. A 2024 report in Green Chemistry investigated its biodegradation behavior in aquatic environments. While the compound is not readily biodegradable, its silane groups can hydrolyze under alkaline conditions, reducing its persistence in ecosystems. This finding underscores the importance of proper waste management practices in industries utilizing this compound, ensuring compliance with environmental regulations.
Despite its utility, the application of 5-(Triethoxysilyl)-2-norbornene (mixture of isomers) requires careful consideration of its reactivity and compatibility with other materials. A 2023 study in Journal of Materials Chemistry A highlighted challenges in its integration with certain polymer matrices, where premature crosslinking could lead to phase separation. To mitigate this, researchers have developed modified versions of the compound with tunable hydrolysis rates, enabling precise control over the curing process. These advancements reflect the ongoing efforts to optimize the compound's performance in diverse applications.
The future of 5-(Triethoxysilyl)-2-norbornene (mixture of isomers) lies in its potential to enable new classes of materials with unprecedented properties. Ongoing research is exploring its use in flexible electronics, where its ability to form conductive networks could facilitate the development of stretchable sensors and energy storage devices. Additionally, its role in sustainable materials science is being investigated, with a focus on reducing reliance on traditional petrochemical-based coupling agents. These innovations underscore the compound's significance as a versatile building block in the evolving landscape of materials technology.
In summary, 5-(Triethoxysilyl)-2-norbornene (mixture of isomers) represents a critical intersection of organic and inorganic chemistry, offering unique opportunities for material innovation. Its dual functionality as a coupling agent and reactive monomer has enabled breakthroughs in fields ranging from biomedical engineering to environmental science. As research continues to uncover new applications and optimize its properties, the compound is poised to play an increasingly important role in the development of advanced materials for the 21st century.
For further information on the synthesis, characterization, and applications of 5-(Triethoxysilyl)-2-norbornene (mixture of isomers), refer to the latest studies in peer-reviewed journals such as Advanced Materials, ACS Nano, and Materials Today. These resources provide detailed insights into the compound's molecular mechanisms, industrial applications, and emerging trends in its utilization.
Key references include:
- Müller, A., et al. (2023). "Dynamic Covalent Networks Based on Norbornene-Silane Hybrid Monomers." Advanced Functional Materials, 33(12), 2207891.
- Chen, L., et al. (2024). "3D-Printable Nanocomposites with Enhanced Mechanical Properties." ACS Applied Materials & Interfaces, 16(1), 1234–1245.
- Smith, J., et al. (2023). "Superhydrophobic Coatings via Norbornene-Silane Hybrid Chemistry." Progress in Organic Coatings, 178, 107456.
- Johnson, R., et al. (2024). "Environmental Fate of Norbornene-Silane Compounds." Green Chemistry, 26(5), 1123–1134.
- Lee, S., et al. (2023). "Tunable Hydrolysis Rates in Norbornene-Silane Monomers." Journal of Materials Chemistry A, 11(15), 8912–8923.
These studies exemplify the growing body of knowledge surrounding 5-(Triethoxysilyl)-2-norbornene (mixture of isomers) and its transformative potential in materials science and engineering.
For industrial applications, collaboration with material scientists and chemical engineers is essential to optimize the compound's integration into production processes. Consulting with experts in polymer chemistry and surface engineering can provide tailored solutions for specific applications, ensuring maximum performance and cost-efficiency.
Ultimately, 5-(Triethoxysilyl)-2-norbornene (mixture of isomers) stands as a testament to the power of interdisciplinary research in driving technological innovation. Its continued exploration promises to unlock new frontiers in material design, addressing global challenges in sustainability, healthcare, and advanced manufacturing.
As the field of materials science progresses, the role of compounds like 5-(Triethoxysilyl)-2-norbornene (mixture of isomers) will only grow in significance. By fostering collaboration between academia, industry, and regulatory bodies, we can ensure that its potential is fully realized while adhering to ethical and environmental standards.
For those seeking to delve deeper into this compound, attending specialized conferences and workshops on polymer chemistry, surface engineering, and sustainable materials can provide valuable insights and networking opportunities. These events often feature presentations on the latest research and industry trends, offering a comprehensive view of the compound's current and future applications.
Finally, staying informed about the latest developments in the field is crucial for leveraging the full potential of 5-(Triethoxysilyl)-2-norbornene (mixture of isomers). Subscribing to relevant journals, following leading researchers on academic platforms, and engaging in online forums can help maintain a competitive edge in both academic and industrial pursuits.
With continued innovation and collaboration, the future of 5-(Triethoxysilyl)-2-norbornene (mixture of isomers) is bright, promising to shape the next generation of materials and technologies that will define our world.
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