Cas no 152763-53-6 (Silanamine,1,1,1-trimethyl-N-(trimethylsilyl)-, thulium(3+) salt (3:1))
Silanamine,1,1,1-trimethyl-N-(trimethylsilyl)-, thulium(3+) salt (3:1) Chemical and Physical Properties
Names and Identifiers
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- Silanamine,1,1,1-trimethyl-N-(trimethylsilyl)-, thulium(3+) salt (3:1)
- bis(trimethylsilyl)azanide,thulium(3+)
- Thulium(3+) bis(trimethylsilyl)amide
- Thulium tris[bis(trimethylsilyl)amide]
- TRIS(N N-BIS(TRIMETHYLSILYL)AMIDE)THUL&
- Tris[N,N-bis(trimethylsilyl)amide]thulium
- Tris[N,N-bis(triMethylsilyl)aMide]thuliuM [[(CH3)3Si]2N]3TM
- Tris[N,N-bis(trimethylsilyl)amide]thulium [[(CH3)3Si]2N]3Tm FW 650.09 M.p. 159-1640C
- bis(trimethylsilyl)azanide;thulium(3+)
- DTXSID40403450
- 152763-53-6
- Tris[N,N-bis(trimethylsilyl)amide]thulium(III)
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- MDL: MFCD03427094
- Inchi: 1S/3C6H18NSi2.Tm/c3*1-8(2,3)7-9(4,5)6;/h3*1-6H3;/q3*-1;+3
- InChI Key: NPNASPVXRLXTMF-UHFFFAOYSA-N
- SMILES: [Tm+3].[Si](C)(C)(C)[N-][Si](C)(C)C.[Si](C)(C)(C)[N-][Si](C)(C)C.[Si](C)(C)(C)[N-][Si](C)(C)C
Computed Properties
- Exact Mass: 649.227552g/mol
- Monoisotopic Mass: 649.227552g/mol
- Isotope Atom Count: 0
- Hydrogen Bond Donor Count: 0
- Hydrogen Bond Acceptor Count: 3
- Heavy Atom Count: 28
- Rotatable Bond Count: 6
- Complexity: 297
- Covalently-Bonded Unit Count: 4
- Defined Atom Stereocenter Count: 0
- Undefined Atom Stereocenter Count : 0
- Defined Bond Stereocenter Count: 0
- Undefined Bond Stereocenter Count: 0
- Surface Charge: 0
- Tautomer Count: nothing
- XLogP3: nothing
- Topological Polar Surface Area: 3?2
Experimental Properties
- Color/Form: Light green solid
- Melting Point: 159-164?°C (lit.)
- Flash Point: Fahrenheit: 35.6 ° f
Celsius: 2 ° c - Solubility: Not determined
Silanamine,1,1,1-trimethyl-N-(trimethylsilyl)-, thulium(3+) salt (3:1) Security Information
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Symbol:
- Signal Word:Danger
- Hazard Statement: H228-H261-H314
- Warning Statement: P210-P231+P232-P280-P305+P351+P338-P310-P422
- Hazardous Material transportation number:UN 3396 4.1(4.3) / PGII
- WGK Germany:3
- Hazard Category Code: 11-14/15-34
- Safety Instruction: 7/8-16-26-36/37/39-43-45
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Hazardous Material Identification:
- Risk Phrases:R11-14/15-34
- Safety Term:S16-26-36/37/39-43-45-7/8
- Storage Condition:storage at -4℃ (1-2weeks), longer storage period at -20℃ (1-2years)
Silanamine,1,1,1-trimethyl-N-(trimethylsilyl)-, thulium(3+) salt (3:1) Pricemore >>
| Related Categories | No. | Product Name | Cas No. | Purity | Specification | Price | update time | Inquiry |
|---|---|---|---|---|---|---|---|---|
| SHENG KE LU SI SHENG WU JI SHU | sc-229659-1g |
Tris[N,N-bis(trimethylsilyl)amide]thulium(III), |
152763-53-6 | 1g |
¥1429.00 | 2023-09-05 | ||
| SHENG KE LU SI SHENG WU JI SHU | sc-229659-1 g |
Tris[N,N-bis(trimethylsilyl)amide]thulium(III), |
152763-53-6 | 1g |
¥1,429.00 | 2023-07-10 |
Silanamine,1,1,1-trimethyl-N-(trimethylsilyl)-, thulium(3+) salt (3:1) Related Literature
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A. B. F. da Silva,K. Capelle Phys. Chem. Chem. Phys., 2009,11, 4564-4569
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Maomao Hou,Fenglin Zhong,Qiu Jin,Enjiang Liu,Jie Feng,Tengyun Wang,Yue Gao RSC Adv., 2017,7, 34392-34400
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Vishwesh Venkatraman,Marco Foscato,Vidar R. Jensen,Bj?rn K?re Alsberg J. Mater. Chem. A, 2015,3, 9851-9860
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Albertus D. Handoko,Khoong Hong Khoo,Teck Leong Tan,Hongmei Jin,Zhi Wei Seh J. Mater. Chem. A, 2018,6, 21885-21890
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Jason Y. C. Lim,Yong Yu,Guorui Jin,Kai Li,Yi Lu,Jianping Xie Nanoscale Adv., 2020,2, 3921-3932
Additional information on Silanamine,1,1,1-trimethyl-N-(trimethylsilyl)-, thulium(3+) salt (3:1)
Introduction to Silanamine,1,1,1-trimethyl-N-(trimethylsilyl)-, thulium(3+) salt (3:1) and Its Applications in Modern Chemistry
Chemistry continues to evolve with the discovery and application of novel compounds that push the boundaries of material science and pharmaceutical research. One such compound, Silanamine,1,1,1-trimethyl-N-(trimethylsilyl)-, thulium(3+) salt (3:1), has garnered significant attention due to its unique structural properties and potential applications. This compound, identified by the CAS number 152763-53-6, represents a fascinating intersection of organosilicon chemistry and coordination chemistry, offering insights into the development of advanced materials and therapeutic agents.
The molecular structure of Silanamine,1,1,1-trimethyl-N-(trimethylsilyl)-, thulium(3+) salt (3:1) is characterized by a trimethylsilyl-substituted silanamine backbone coordinated to a thulium(3+) ion. This unique arrangement imparts distinct electronic and steric properties to the compound, making it a valuable candidate for various chemical transformations. The presence of the trimethylsilyl group enhances the stability of the silanamine moiety, while the coordination with thulium(3+) introduces luminescent properties that are increasingly relevant in areas such as bioimaging and catalysis.
In recent years, there has been growing interest in the use of lanthanide complexes for their luminescent properties. Thulium(3+) ions, in particular, have been studied for their ability to emit light in the near-infrared region, which is highly desirable for biological imaging applications due to its deeper tissue penetration. The compound Silanamine,1,1,1-trimethyl-N-(trimethylsilyl)-, thulium(3+) salt (3:1) leverages this property by serving as a luminescent probe in cellular studies. Researchers have utilized this compound to track biological processes in real-time, providing valuable insights into cellular dynamics and metabolic pathways.
Beyond its applications in bioimaging, Silanamine,1,1,1-trimethyl-N-(trimethylsilyl)-, thulium(3+) salt (3:1) has shown promise in the field of catalysis. The coordination environment around the thulium(3+) ion can be tailored to facilitate various organic transformations. For instance, studies have demonstrated its effectiveness in promoting cross-coupling reactions and oxidation processes under mild conditions. These reactions are crucial in synthetic chemistry and have implications for the development of new pharmaceuticals and agrochemicals.
The stability provided by the trimethylsilyl group also makes this compound a suitable candidate for industrial applications. In material science, organosilicon compounds are widely used due to their thermal stability and resistance to degradation. The incorporation of thulium(3+) into these frameworks opens up possibilities for creating novel materials with enhanced functional properties. For example, researchers are exploring its use in the development of photovoltaic materials and sensors that rely on luminescent properties for detection.
The synthesis of Silanamine,1,1,1-trimethyl-N-(trimethylsilyl)-, thulium(3+) salt (3:1) is another area of active research. The process involves carefully controlled coordination reactions between silanamine derivatives and thulium salts. Recent advancements in synthetic methodologies have improved the yield and purity of this compound, making it more accessible for practical applications. These improvements are driven by the need for high-quality materials in fields such as pharmaceuticals and electronics.
In conclusion, Silanamine,1,1,1-trimethyl-N-(trimethylsilyl)-, thulium(3+) salt (3:1), with its CAS number 152763-53-6, represents a significant advancement in the field of organosilicon chemistry and coordination chemistry. Its unique properties make it a versatile tool for applications ranging from bioimaging to catalysis and material science. As research continues to uncover new uses for this compound,its importance is likely to grow,further solidifying its role as a cornerstone in modern chemical innovation.
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