• 1. Fe3O4/Au/Fe3O4 nanoflowers exhibiting tunable saturation magnetization and enhanced bioconjugation
  Feng Shi,Kunping Yan,Mingli Peng,Xiao Cheng,Yanling Luo,Xuemei Chen,V. A. L. Roy,Zuankai Wang Nanoscale, 2012,4, 747-751
• 2. Fe3O4 nanoclusters highly dispersed on a porous graphene support as an additive for improving the hydrogen storage properties of LiBH4?
  Guang Xu,Wei Zhang,Ying Zhang,Xiaoxia Zhao,Ping Wen,Di Ma RSC Adv., 2018,8, 19353-19361
• 3. Distinct roles of SNARE-mimicking lipopeptides during initial steps of membrane fusion?
  Alena Koukalová,?árka Pokorná,Aimee L. Boyle,Nestor Lopez Mora,Alexander Kros,Martin Hof,Radek ?achl Nanoscale, 2018,10, 19064-19073
• 4. Emerging investigator series: first-principles and thermodynamics comparison of compositionally-tuned delafossites: cation release from the (001) surface of complex metal oxides?
  Joseph W. Bennett,Diamond T. Jones,Blake G. Hudson,Joshua Melendez-Rivera,Robert J. Hamers,Sara E. Mason Environ. Sci.: Nano, 2020,7, 1642-1651
• 5. Enabling stable MnO2 matrix for aqueous zinc-ion battery cathodes?
  Yiding Jiao,Liqun Kang,Jasper Berry-Gair,Kit McColl,Jianwei Li,Haobo Dong,Hao Jiang,Ryan Wang,Furio Corà,Dan J. L. Brett,Ivan P. Parkin J. Mater. Chem. A, 2020,8, 22075-22082

• Catalysts and Inorganic Chemicals Inorganic Compounds
• Catalysts and Inorganic Chemicals Catalysts

Carbonylchlorobis(Triphenylphosphine)Iridium(I) (CAS No. 14871-41-1): Properties, Applications, and Market Insights

Carbonylchlorobis(Triphenylphosphine)Iridium(I) (CAS No. 14871-41-1) is a highly specialized organometallic compound that has garnered significant attention in both academic research and industrial applications. This compound, often abbreviated as Ir(CO)Cl(PPh3)2, is a coordination complex featuring iridium in the +1 oxidation state, coordinated by a carbonyl ligand, a chloride ion, and two triphenylphosphine groups. Its unique structure and reactivity make it a valuable tool in catalysis, material science, and photochemistry.

The physical and chemical properties of Carbonylchlorobis(Triphenylphosphine)Iridium(I) contribute to its versatility. It typically appears as a yellow to orange crystalline solid, soluble in organic solvents like dichloromethane and toluene but insoluble in water. The compound exhibits stability under inert atmospheres but can degrade upon prolonged exposure to air or moisture. Its molecular weight is approximately 796.19 g/mol, and it is often characterized using techniques such as NMR spectroscopy, X-ray crystallography, and infrared spectroscopy, which confirms the presence of the carbonyl group through its characteristic stretching frequency.

One of the most prominent applications of Carbonylchlorobis(Triphenylphosphine)Iridium(I) is in homogeneous catalysis. The compound serves as a precursor for various iridium-based catalysts used in hydrogenation, carbonylation, and C-H bond activation reactions. Researchers have explored its utility in green chemistry initiatives, where it facilitates sustainable synthetic routes with high atom economy and reduced waste. For instance, it has been employed in the catalytic conversion of biomass-derived feedstocks into value-added chemicals, aligning with the global push toward renewable resources.

In the realm of photophysics and optoelectronics, Ir(CO)Cl(PPh3)2 has shown promise due to its luminescent properties. It is a subject of interest in the development of organic light-emitting diodes (OLEDs) and photocatalytic systems. The compound's ability to undergo photoinduced electron transfer makes it a candidate for solar energy conversion technologies, a hot topic given the increasing demand for clean energy solutions. Recent studies have also investigated its potential in light-driven catalysis, where it can mediate reactions under mild conditions, reducing energy consumption.

The market dynamics for Carbonylchlorobis(Triphenylphosphine)Iridium(I) reflect its niche but growing demand. As industries seek more efficient and sustainable catalytic processes, the need for high-purity iridium complexes has risen. Suppliers often highlight its role in R&D laboratories and specialty chemical manufacturing, where it is used to develop novel materials and pharmaceuticals. Pricing trends are influenced by the availability of iridium, a rare and expensive platinum-group metal, making cost-effective synthesis and recycling methods a focal point for researchers.

Frequently asked questions about Carbonylchlorobis(Triphenylphosphine)Iridium(I) include inquiries about its synthesis methods, stability, and handling precautions. Many users search for alternatives or derivatives that offer similar reactivity but at a lower cost. Others explore its compatibility with other ligands or metals to tailor its properties for specific applications. These queries underscore the compound's adaptability and the ongoing innovation in its use.

In summary, Carbonylchlorobis(Triphenylphosphine)Iridium(I) (CAS No. 14871-41-1) stands out as a multifaceted compound with significant implications in catalysis, energy, and materials science. Its unique properties and applications align with contemporary trends in sustainability and technological advancement, ensuring its continued relevance in both academic and industrial settings. As research progresses, new opportunities for this iridium complex are likely to emerge, further solidifying its role in modern chemistry.

• 16971-33-8(Carbonylchlorohydridotris(triphenylphosphine)ruthenium(Ⅱ))
• 17185-29-4(Carbonylhydridotris(triphenylphosphine)rhodium(I))
• 13007-90-4(dicarbonylbis(triphenylphosphine)nickel)
• 17250-25-8(Hydridocarbonyltris(triphenylphosphine)iridium (I), Ir 19.1%)
• 17442-18-1(Trichlorooxobis(triphenylphosphine)-rhenium)
• 25360-32-1(Carbonyldihydrotris(triphenylphosphine)ruthenium(II))
• 19536-77-7(Iridium,dibromocarbonylhydrobis(triphenylphosphine)-)
• 14917-12-5(Chromium,pentacarbonyl(triphenylphosphine)-, (OC-6-22)-)
• 15318-31-7(Carbon monoxide; iridium; triphenylphosphane; chloride)
• 17035-59-5(Iridium,chlorodihydrotris(triphenylphosphine)-)