Cas no 14647-23-5 (Bis(diphenylphosphino)ethanedichloronickel)
Bis(diphenylphosphino)ethanedichloronickel is a nickel(II) complex featuring a bidentate diphosphine ligand, commonly utilized as a catalyst in cross-coupling and hydrogenation reactions. Its well-defined coordination geometry and air-stable nature enhance reproducibility in synthetic applications. The chelating diphenylphosphinoethane backbone ensures robust metal-ligand interactions, improving catalytic efficiency in organic transformations. This compound is particularly valued for its selectivity in C-C and C-X bond-forming reactions, making it useful in pharmaceutical and fine chemical synthesis. Its stability under mild conditions and compatibility with diverse substrates contribute to its broad utility in homogeneous catalysis. Proper handling under inert conditions is recommended to maintain performance.
14647-23-5 structure
Product Name:Bis(diphenylphosphino)ethanedichloronickel
CAS No:14647-23-5
MF:C26H24Cl2NiP2
MW:528.015687942505
MDL:MFCD00013313
CID:49891
Update Time:2025-05-28
Bis(diphenylphosphino)ethanedichloronickel Chemical and Physical Properties
Names and Identifiers
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- 1,2-Bis(diphenylphosphino)ethane nickel(II) chloride
- Dichloro[bis(1,2-diphenylphosphino)ethane]nickel(II)
- [1,2-Bis(diphenylphosphino)ethane]nickel(II) Dichloride
- [1,2-Bis(diphenylphosphino)ethane]dichloronickel(II)
- [1,2-Bis(diphenylphosphino)ethane]dichloronickel
- [Bis(diphenylphosphino)ethane]dichloronickel
- 2-diphenylphosphanylethyl(diphenyl)phosphane,nickel(2+),dichloride
- Dichloro[1,2-bis(diphenylphosphino)ethane]nickel(II)
- 1,2-Ethylenebis(diphenylphosphine)nickel dichloride
- Nickel 1,2-Bis(diphenylphosphino)ethane dichloride
- [1,2-Bis(diphenylphosphino)ethane]nickel(II) chloride
- dppeNiCl2
- Nickel,dichloro[1,2-ethanediylbis[diphenylphosphine]-P,P']-, (SP-4-2)-
- Nickel,dichloro[ethylenebis[diphenylphosphine]]- (7CI)
- Nickel,dichloro[ethylenebis[diphenylphosphine]]-, cis- (8CI)
- (Bis(diphenylphosphino)ethane)dichloronickel
- 1,2-Bis(diphenylphosphino)ethanenickel dichloride
- Dichloro[1,2-bis(diphenylphosphino)ethane]nickel
- Dichloro[1,2-ethanediylbis[diphenylphosphine]-P,P']nickel
- Dichloro[1,2-ethanediylbis[diphenylphosphine]]nickel
- Dichloro[ethylenebis[diphenylphosphine]]nickel
- Dichlorobis[(diphenylphosphino)ethane]nickel(II)
- cis-(1,2-Bis(diphenylphosphino)ethane)dichloronickel
- 1,2-Bis-(Diphenylphosphino)Eth
- 1,2-Bis-(Diphenylphosphino)EthaneDichloroNickel
- 1,2-Bis (diphenylphosphino)ethane]dichlornickel
- 1,2-Bis-(diphenylphosphino)-ethane nickel chloride
- 1,2-Bis(diphenylphosphino)ethane nickel(II) chlori
- [1,2-Bis(diphenylphosphino)ethane]dichloronickel(Ⅱ)
- Phosphine,1,2-ethanediylbis[diphenyl-, nickel complex
- Nickel1,2-Bis(diphenylphosphino)ethane dichloride
- [1,2-Bis(diphenylphosphino)ethane]nickel(II)chloride
- Bis(diphenylphosphino)ethanedichloronickel
-
- MDL： MFCD00013313
- Inchi： 1S/C26H24P2.2ClH.Ni/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;2*1H;/q;;;+2/p-2
- InChI Key： XXECWTBMGGXMKP-UHFFFAOYSA-L
- SMILES： [Ni+2].[Cl-].[Cl-].P(C1C=CC=CC=1)(C1C=CC=CC=1)CCP(C1C=CC=CC=1)C1C=CC=CC=1
Computed Properties
- Exact Mass: 526.00800
- Monoisotopic Mass: 526.008
- Isotope Atom Count: 0
- Hydrogen Bond Donor Count: 0
- Hydrogen Bond Acceptor Count: 0
- Heavy Atom Count: 31
- Rotatable Bond Count: 7
- Complexity: 336
- Covalently-Bonded Unit Count: 4
- Defined Atom Stereocenter Count: 0
- Undefined Atom Stereocenter Count : 0
- Defined Bond Stereocenter Count: 0
- Undefined Bond Stereocenter Count: 0
- Topological Polar Surface Area: 0A^2
- Surface Charge: 0
- Tautomer Count: nothing
- XLogP3: nothing
Experimental Properties
- Color/Form: Orange powder
- Melting Point: 263-265?°C (lit.)
- Boiling Point: 514.8°Cat760mmHg
- Flash Point: 281.7°C
- Water Partition Coefficient: Insoluble
- PSA: 27.18000
- LogP: -0.73980
- Solubility: Insoluble in water
Bis(diphenylphosphino)ethanedichloronickel Security Information
-
Symbol:
- Prompt：dangerous
- Signal Word：Danger
- Hazard Statement： H302,H312,H315,H319,H332,H334,H335,H350
- Warning Statement： P201,P261,P280,P305+P351+P338,P308+P313
- Hazardous Material transportation number：NONH for all modes of transport
- WGK Germany：3
- Hazard Category Code： 45-20/21/22-36/37/38-42/43
- Safety Instruction： S53-S22-S26-S36-S45-S52
-
Hazardous Material Identification：
- Risk Phrases：R45; R20/21/22; R36/37/38; R40; R42/43
- Storage Condition：Store at room temperature
- Safety Term：S52;S22;S26;S36;S45
Bis(diphenylphosphino)ethanedichloronickel Pricemore >>
| Related Categories | No. | Product Name | Cas No. | Purity | Specification | Price | update time | Inquiry |
|---|---|---|---|---|---|---|---|---|
| SU ZHOU XIN JIA YUAN HUA XUE Technology Co., Ltd. | 600058-5g |
Bis(diphenylphosphino)ethanedichloronickel |
14647-23-5 | 98% | 5g |
￥125.0 | 2024-07-19 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | B2225-25g |
Bis(diphenylphosphino)ethanedichloronickel |
14647-23-5 | 96.0%(T) | 25g |
￥2850.0 | 2022-05-30 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | B2225-5g |
Bis(diphenylphosphino)ethanedichloronickel |
14647-23-5 | 96.0%(T) | 5g |
￥845.0 | 2022-05-30 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | B2225-1g |
Bis(diphenylphosphino)ethanedichloronickel |
14647-23-5 | 96.0%(T) | 1g |
￥320.0 | 2022-05-30 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | B019R-5g |
Bis(diphenylphosphino)ethanedichloronickel |
14647-23-5 | 96% | 5g |
￥55.0 | 2022-05-30 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | B019R-25g |
Bis(diphenylphosphino)ethanedichloronickel |
14647-23-5 | 96% | 25g |
￥139.0 | 2022-05-30 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | B019R-100g |
Bis(diphenylphosphino)ethanedichloronickel |
14647-23-5 | 96% | 100g |
￥450.0 | 2022-05-30 | |
| SHANG HAI A LA DING SHENG HUA KE JI GU FEN Co., Ltd. | D101082-1g |
Bis(diphenylphosphino)ethanedichloronickel |
14647-23-5 | 98% | 1g |
￥29.90 | 2023-09-03 | |
| SHANG HAI A LA DING SHENG HUA KE JI GU FEN Co., Ltd. | D101082-25g |
Bis(diphenylphosphino)ethanedichloronickel |
14647-23-5 | 98% | 25g |
￥70.90 | 2023-09-03 | |
| SHANG HAI A LA DING SHENG HUA KE JI GU FEN Co., Ltd. | D101082-100g |
Bis(diphenylphosphino)ethanedichloronickel |
14647-23-5 | 98% | 100g |
￥257.90 | 2023-09-03 |
Bis(diphenylphosphino)ethanedichloronickel Suppliers
Tiancheng Chemical (Jiangsu) Co., Ltd
Gold Member
Audited Supplier
(CAS:14647-23-5)1,2-Bis(diphenylphosphinoethane)nickel(II) chloride
Order Number:LE1967;LE1775334
Stock Status:in Stock
Quantity:25KG,200KG,1000KG
Purity:99%
Pricing Information Last Updated:Friday, 20 June 2025 11:41
Price ($):discuss personally
Email:[email protected]
Suzhou Senfeida Chemical Co., Ltd
Gold Member
Audited Supplier
(CAS:14647-23-5)[1,2-Bis(diphenylphosphino)ethane]dichloronickel
Order Number:sfd10435
Stock Status:in Stock
Quantity:200KG
Purity:99%
Pricing Information Last Updated:Friday, 19 July 2024 14:35
Price ($):discuss personally
Email:[email protected]
Bis(diphenylphosphino)ethanedichloronickel Related Literature
-
1. Dimorphs of [1,2-bis(diphenylphosphino)ethane]dichloronickel(II)Richard Busby,Michael B. Hursthouse,Penelope S. Jarrett,Christian W. Lehmann,K. M. Abdul Malik,Coral Phillips J. Chem. Soc. Dalton Trans. 1993 3767
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Mahesh P. Bhatt,Harsha D. Magurudeniya,Prakash Sista,Elena E. Sheina,Malika Jeffries-EL,Benjamin G. Janesko,Richard D. McCullough,Mihaela C. Stefan J. Mater. Chem. A 2013 1 12841
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In-Hwan Lee,Pitchamuthu Amaladass,Tae-Lim Choi Chem. Commun. 2014 50 7945
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Annelien Van Oosten,Cynthia Verduyckt,Julien De Winter,Pascal Gerbaux,Guy Koeckelberghs Soft Matter 2023 19 3794
-
Ryouta Tatumi,Tomoki Akita,Hisashi Fujihara Chem. Commun. 2006 3349
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14647-23-5 (Bis(diphenylphosphino)ethanedichloronickel) Related Products
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Recommended suppliers
Tiancheng Chemical (Jiangsu) Co., Ltd
(CAS:14647-23-5)1,2-Bis(diphenylphosphinoethane)nickel(II) chloride
Purity:99%/99%
Quantity:25KG,200KG,1000KG/25KG,200KG,1000KG
Price ($):Inquiry/Inquiry
Suzhou Senfeida Chemical Co., Ltd
(CAS:14647-23-5)[1,2-Bis(diphenylphosphino)ethane]dichloronickel
Purity:99%
Quantity:200KG
Price ($):Inquiry