Cas no 13938-94-8 (Carbonylbis(triphenylphosphine)rhodium(I) Chloride)
Carbonylbis(triphenylphosphine)rhodium(I) chloride is a well-defined rhodium(I) complex widely used in homogeneous catalysis and organic synthesis. Its key advantages include high stability under inert conditions and efficient catalytic activity in hydrogenation, hydroformylation, and carbonylation reactions. The presence of both carbonyl and triphenylphosphine ligands provides a balanced electronic environment, enhancing selectivity in transformations involving alkenes and other unsaturated substrates. This complex is particularly valued for its reproducibility in catalytic cycles and compatibility with a range of solvents. Its crystalline form ensures ease of handling and precise stoichiometric use in research and industrial applications.
13938-94-8 structure
Product Name:Carbonylbis(triphenylphosphine)rhodium(I) Chloride
CAS No:13938-94-8
MF:C37H32ClOP2Rh
MW:692.955412864685
MDL:MFCD00044273
CID:49552
PubChem ID:24852243
Update Time:2025-06-08
Carbonylbis(triphenylphosphine)rhodium(I) Chloride Chemical and Physical Properties
Names and Identifiers
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- Formylbis(triphenylphosphoranyl)rhodium(IV) chloride
- Carbonylbis(triphenylphosphine)rhodium(I) chloride~Carbonylchlorobis(triphenylphosphine)rhodium(I)~Chlorocarbonylbis(triphenylphosphine)rhodium(I)
- trans-Bis(triphenylphosphine)rhodium(I) carbonyl chloride
- carbonylchlorobis(triphenylphosphine)-rhodium(I),
- Chlorocarbonylbis(triphenylphosphine)rhodium (I)
- Carbonylbis(triphenylphosphine)rhodium(I) Chloride
- Bis(triphenylphosphine)rhodium(I) carbonyl chloride
- Chlorocarbonylbis (triphenylphosphine)
- Formylbis(triphenylphosphoranyl)-rhodium(IV) chloride
- Potassium Hexabromo Iridate (IV)
- Rhodium(I) tris(triphenylphosphine) chloride
- Bis(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate
- Bis(triphenylphosphine)carbonylrhodium(I) Chloride
- Carbonylchlorobis(triphenylphosphine)rhodium(I)
- methanone,rhodium(2+),triphenylphosphanium,chloride
- Rhodiumbis(triphenylphosphine) carbonyl chloride
- RhCl(CO)(PPh3)2
- Rhodium,chlorocarbonylbis(triphenylphosphine)- (6CI,7CI)
- Bis(triphenylphosphine)carbonylchlororhodium
- Bis(triphenylphosphine)carbonylchlororhodium(I)
- Bis(triphenylphosphine)carbonylrhodium chloride
- Bis(triphenylphosphine)rhodiumcarbonyl chloride
- Carbonylbis(triphenylphosphine)rhodium chloride
- Carbonylchlorobis(triphenylphosphine)rhodium
- Chlorocarbonylbis(triphenylphosphine)rhodium
- NSC 168792
- Rhodium carbonylbis(triphenylphosphine) chloride
- Bis(Triphenylphosphine)rhodium(I) carbon
- BIS(TRIPHENYLPHOSPHINE)CARBONYLRHODIUM(I
- Carbonychlorobis(triphenylphosphine)rhodium
- Rhodium, carbonylchlorobis(triphenylphosphine)-
- Carconylchlorobis(triphenylphosphine)rhodium(I)
- Carbonylbis(triphenylphosphine)rhodium(I)chloride
- Chlorocarbonylbis(triphenylphosphine)rhodium(I)
- Carbonylbis(tripheny
- Chlorocarbonyl bis(triphenylphosphine) rhodium
- AC-4991
- MFCD00044273
- formaldehyde;rhodium;triphenylphosphane;chloride
- AKOS025402107
- 13938-94-8
- HPWKFRMRYWEJBC-UHFFFAOYSA-M
- Chlorocarbonylbis(triphenylphosphine) rhodium(I)
- Chlorocarbonylbis(triphenylphosphine) rhodium
-
- MDL： MFCD00044273
- Inchi： 1S/2C18H15P.CH2O.ClH.Rh/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;;/h2*1-15H;1H2;1H;/p-1
- InChI Key： HPWKFRMRYWEJBC-UHFFFAOYSA-M
- SMILES： [Rh].[Cl-].P(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1.P(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1.O=C
Computed Properties
- Exact Mass: 692.06700
- Monoisotopic Mass: 692.067
- Isotope Atom Count: 0
- Hydrogen Bond Donor Count: 0
- Hydrogen Bond Acceptor Count: 0
- Heavy Atom Count: 42
- Rotatable Bond Count: 6
- Complexity: 204
- Covalently-Bonded Unit Count: 5
- Defined Atom Stereocenter Count: 0
- Undefined Atom Stereocenter Count : 0
- Defined Bond Stereocenter Count: 0
- Undefined Bond Stereocenter Count: 0
- Topological Polar Surface Area: 17.1A^2
Experimental Properties
- Color/Form: Yellow crystals. Stable in air.
- Melting Point: 227°C(dec.)(lit.)
- Boiling Point: No data available
- Flash Point: °C
- Solubility: Soluble in acetone, chloroform, ethanol
- PSA: 27.18000
- LogP: 6.92660
- Sensitiveness: Sensitive to humidity
- Solubility: Not determined
Carbonylbis(triphenylphosphine)rhodium(I) Chloride Security Information
-
Symbol:
- Prompt：warning
- Signal Word：warning
- Hazard Statement： H315-H319
- Warning Statement： P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313
- Hazardous Material transportation number：NONH for all modes of transport
- WGK Germany：3
- Hazard Category Code： R20/21/22
- Safety Instruction： S24/25
-
Hazardous Material Identification：
- Safety Term：6.1
- Packing Group：I; II; III
- Risk Phrases：R20/21/22
- Packing Group：I; II; III
- Hazard Level：6.1
- Storage Condition：Store at 4°C,-4At ℃Store…Better
Carbonylbis(triphenylphosphine)rhodium(I) Chloride Customs Data
- HS CODE：28439090
- Customs Data：
China Customs Code:
28439090
Carbonylbis(triphenylphosphine)rhodium(I) Chloride Pricemore >>
| Related Categories | No. | Product Name | Cas No. | Purity | Specification | Price | update time | Inquiry |
|---|---|---|---|---|---|---|---|---|
| SHANG HAI A LA DING SHENG HUA KE JI GU FEN Co., Ltd. | B113668-1g |
Carbonylbis(triphenylphosphine)rhodium(I) Chloride |
13938-94-8 | Rh ≥14.90% | 1g |
￥4737.90 | 2023-09-04 | |
| SHANG HAI A LA DING SHENG HUA KE JI GU FEN Co., Ltd. | B113668-250mg |
Carbonylbis(triphenylphosphine)rhodium(I) Chloride |
13938-94-8 | Rh ≥14.90% | 250mg |
￥1647.90 | 2023-09-04 | |
| SHANG HAI A LA DING SHENG HUA KE JI GU FEN Co., Ltd. | B113668-5g |
Carbonylbis(triphenylphosphine)rhodium(I) Chloride |
13938-94-8 | Rh ≥14.90% | 5g |
￥16479.90 | 2023-09-04 | |
| TI XI AI ( SHANG HAI ) HUA CHENG GONG YE FA ZHAN Co., Ltd. | B1692-1G |
Carbonylbis(triphenylphosphine)rhodium(I) Chloride |
13938-94-8 | 1g |
￥1290.00 | 2024-04-17 | ||
| Alichem | A019121889-1g |
Formylbis(triphenylphosphoranyl)rhodium(IV) chloride |
13938-94-8 | 95% | 1g |
165.00 USD | 2021-05-31 | |
| Alichem | A019121889-5g |
Formylbis(triphenylphosphoranyl)rhodium(IV) chloride |
13938-94-8 | 95% | 5g |
499.20 USD | 2021-05-31 | |
| Alichem | A019121889-10g |
Formylbis(triphenylphosphoranyl)rhodium(IV) chloride |
13938-94-8 | 95% | 10g |
772.20 USD | 2021-05-31 | |
| Chemenu | CM102898-1g |
Chlorocarbonylbis(triphenylphosphine)rhodium(I) |
13938-94-8 | 95% | 1g |
$168 | 2021-08-06 | |
| Chemenu | CM102898-5g |
Chlorocarbonylbis(triphenylphosphine)rhodium(I) |
13938-94-8 | 95% | 5g |
$449 | 2021-08-06 | |
| Chemenu | CM102898-10g |
Chlorocarbonylbis(triphenylphosphine)rhodium(I) |
13938-94-8 | 95% | 10g |
$729 | 2021-08-06 |
Carbonylbis(triphenylphosphine)rhodium(I) Chloride Suppliers
Suzhou Senfeida Chemical Co., Ltd
Gold Member
Audited Supplier
(CAS:13938-94-8)Carbonylbis(triphenylphosphine)rhodium(I) chloride
Order Number:sfd16740
Stock Status:in Stock
Quantity:200kg
Purity:99.9%
Pricing Information Last Updated:Friday, 19 July 2024 14:37
Price ($):discuss personally
Email:[email protected]
Carbonylbis(triphenylphosphine)rhodium(I) Chloride Related Literature
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Wei Zhou,Dehua He Green Chem. 2009 11 1146
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Masaki Okada,Katsuhiko Takeuchi,Kazuhiro Matsumoto,Tomoharu Oku,Jun-Chul Choi Org. Biomol. Chem. 2021 19 8727
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Michael J. Bartlett,Benjamin J. Frogley,Anthony F. Hill,Manab Sharma,Matthew K. Smith,Jas S. Ward Dalton Trans. 2019 48 16534
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4. Activation of H2 by halogenocarbonylbis(phosphine)rhodium(I) complexes. The use of parahydrogen induced polarisation to detect species present at low concentrationPaul D. Morran,Simon B. Duckett,Peter R. Howe,John E. McGrady,Simon A. Colebrooke,Richard Eisenberg,Martin G. Partridge,Joost A. B. Lohman J. Chem. Soc. Dalton Trans. 1999 3949
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Simon B. Duckett,Maria-Dolores Gálvez-López,Robin N. Perutz,Danièle Schott Dalton Trans. 2004 2746
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Recommended suppliers
Suzhou Senfeida Chemical Co., Ltd
(CAS:13938-94-8)Carbonylbis(triphenylphosphine)rhodium(I) chloride
Purity:99.9%
Quantity:200kg
Price ($):Inquiry