Cas no 13499-05-3 (Tetrachlorohafnium)
Tetrachlorohafnium Chemical and Physical Properties
Names and Identifiers
-
- hafnium tetrachloride
- Hafnium chloride
- Hafnium(IV) chloride
- Hafnium chloride(HfCl4)
- Hafnium(IV) chloride,-80 mesh
- HAFNIUMANDITSCOMPOUNDS
- HfCl4
- Tetrachlorohafnium
- (beta-4)-hafnium chloride
- Hafnium Chloride 98+%
- HAFNIUM CHLORIDE, 98.5%
- HafniuM(IV) chloride 98%
- Hafnium(IV) chloride, purified by sublimation
- Hafnium chloride(HfCl4), (T-4)-
- Hafnium(IV) chloride, 98%
- 13499-05-3
- Hafnium IV Chloride
- Q2628977
- UNII-CNZ9V5JM5H
- 37230-84-5
- Hafnium(IV) chloride, purified by sublimation, 99.9% trace metals basis
- Hafnium(IV) chloride, purum, >=97% (AT)
- EINECS 236-826-5
- EC 236-826-5
- Hafnium(IV) chloride, sublimed grade
- D94750
- Hafnium chloride (HfCl4), (T-4)-
-
- MDL: MFCD00011034
- Inchi: 1S/4ClH.Hf/h4*1H;/q;;;;+4/p-4
- InChI Key: PDPJQWYGJJBYLF-UHFFFAOYSA-J
- SMILES: [Hf](Cl)(Cl)(Cl)Cl
Computed Properties
- Exact Mass: 319.82200
- Monoisotopic Mass: 319.82196
- Isotope Atom Count: 0
- Hydrogen Bond Donor Count: 0
- Hydrogen Bond Acceptor Count: 0
- Heavy Atom Count: 5
- Rotatable Bond Count: 0
- Complexity: 19.1
- Covalently-Bonded Unit Count: 1
- Defined Atom Stereocenter Count: 0
- Undefined Atom Stereocenter Count : 0
- Defined Bond Stereocenter Count: 0
- Undefined Bond Stereocenter Count: 0
- Surface Charge: 0
- Tautomer Count: nothing
- XLogP3: nothing
- Topological Polar Surface Area: 0
Experimental Properties
- Color/Form: Colorless crystals
- Density: 1.91 g/cm3
- Melting Point: 432?°C (lit.)
- Boiling Point: 315.47°C (estimate)
- Flash Point: °C
- Solubility: Soluble in methanol and acetone.
- Water Partition Coefficient: Soluble in water, methanol and acetone.
- PSA: 0.00000
- LogP: 2.75800
- Merck: 14,4588
- Sensitiveness: Moisture Sensitive
- Vapor Pressure: 1 mmHg ( 190 °C)
- Solubility: Strong reaction with water
Tetrachlorohafnium Security Information
-
Symbol:
- Signal Word:Danger
- Hazard Statement: H314
- Warning Statement: P280-P305+P351+P338-P310
- Hazardous Material transportation number:UN 3260 8/PG 2
- WGK Germany:3
- Hazard Category Code: 34
- Safety Instruction: S26; S36/37/39; S45
- FLUKA BRAND F CODES:9-21
-
Hazardous Material Identification:
- Packing Group:II
- Hazard Level:8
- Risk Phrases:R34
- Packing Group:II
- Safety Term:8
- HazardClass:8
- PackingGroup:II
- TSCA:Yes
- Storage Condition:Moisture Sensitive. Store under Nitrogen. Ambient temperatures.
Tetrachlorohafnium Pricemore >>
| Related Categories | No. | Product Name | Cas No. | Purity | Specification | Price | update time | Inquiry |
|---|---|---|---|---|---|---|---|---|
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | 72-0751-10g |
Tetrachlorohafnium |
13499-05-3 | sublimedgrade(99.9+%-Hf,<1.0%Zr) | 10g |
826CNY | 2021-05-10 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | 72-0752-1g |
Tetrachlorohafnium |
13499-05-3 | sublimedgrade(99.9+%-Hf,<0.05%Zr) | 1g |
470CNY | 2021-05-10 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | 72-0752-25g |
Tetrachlorohafnium |
13499-05-3 | sublimedgrade(99.9+%-Hf,<0.05%Zr) | 25g |
4702CNY | 2021-05-10 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | 72-0752-5g |
Tetrachlorohafnium |
13499-05-3 | sublimedgrade(99.9+%-Hf,<0.05%Zr) | 5g |
1467CNY | 2021-05-10 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | 72-0751-250g |
Tetrachlorohafnium |
13499-05-3 | sublimedgrade(99.9+%-Hf,<1.0%Zr) | 250g |
5187CNY | 2021-05-10 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | 72-0751-50g |
Tetrachlorohafnium |
13499-05-3 | sublimedgrade(99.9+%-Hf,<1.0%Zr) | 50g |
1296CNY | 2021-05-10 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | F-TQ385-1g |
Hafnium(IV)chloride |
13499-05-3 | 99.9% (metals basis), Zr<0.5% | 1g |
¥123.0 | 2022-03-01 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | F-TQ385-5g |
Hafnium(IV)chloride |
13499-05-3 | 99.9% (metals basis), Zr<0.5% | 5g |
¥367.0 | 2022-03-01 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | F-XO945-5g |
Tetrachlorohafnium |
13499-05-3 | 99.5% | 5g |
¥246.0 | 2022-07-28 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | F-XO945-1g |
Tetrachlorohafnium |
13499-05-3 | 99.5% | 1g |
¥113.0 | 2022-07-28 |
Tetrachlorohafnium Suppliers
Tetrachlorohafnium Related Literature
-
Weili Dai,Guangjun Wu,Michael Hunger Chem. Commun., 2015,51, 13779-13782
-
Tengfei Yu,Yuehan Wu,Wei Li,Bin Li RSC Adv., 2014,4, 34134-34143
-
Denis V. Korchagin,Elena A. Yureva,Alexander V. Akimov,Eugenii Ya. Misochko,Gennady V. Shilov,Artem D. Talantsev,Roman B. Morgunov,Alexander A. Shakin,Sergey M. Aldoshin,Boris S. Tsukerblat Dalton Trans., 2017,46, 7540-7548
-
Yukiya Kitayama Polym. Chem., 2014,5, 2784-2792
Additional information on Tetrachlorohafnium
Comprehensive Overview of Tetrachlorohafnium (CAS No. 13499-05-3): Properties, Applications, and Industry Insights
Tetrachlorohafnium (CAS No. 13499-05-3) is an inorganic compound with the chemical formula HfCl4. As a hafnium-based chloride, it plays a critical role in advanced material science, particularly in the semiconductor and aerospace industries. This compound is known for its high thermal stability and reactivity, making it a valuable precursor in chemical vapor deposition (CVD) and atomic layer deposition (ALD) processes. Researchers and manufacturers increasingly focus on hafnium compounds due to their unique electronic properties and compatibility with next-generation technologies.
The growing demand for high-k dielectric materials in microelectronics has spotlighted Tetrachlorohafnium as a key enabler. With the rise of 5G, IoT, and AI-driven hardware, the need for efficient thin-film coatings has surged. HfCl4 is instrumental in producing hafnium oxide (HfO2), a material that outperforms traditional silicon dioxide in gate insulation layers. Industry leaders like Intel and TSMC have integrated hafnium-based solutions into their fabrication processes, underscoring the compound's relevance in modern chip design.
Beyond electronics, Tetrachlorohafnium finds applications in catalysis and ceramic manufacturing. Its ability to form stable complexes with organic ligands makes it useful in polymerization reactions. Recent studies also explore its potential in energy storage systems, such as solid-state batteries, where hafnium-doped electrolytes show improved ionic conductivity. These innovations align with global trends toward sustainable energy solutions, a topic dominating scientific and industrial discourse.
From a synthesis perspective, 13499-05-3 is typically produced by direct chlorination of hafnium metal or hafnium oxide at elevated temperatures. The compound's purity is paramount, especially for semiconductor-grade applications, where trace contaminants can compromise device performance. Advanced purification techniques, including sublimation and zone refining, are employed to meet stringent industry standards. This emphasis on quality control reflects broader shifts toward precision chemistry in high-tech sectors.
Environmental and safety considerations surrounding Tetrachlorohafnium are frequently searched topics. While the compound requires careful handling due to its hygroscopic nature, modern containment and automation technologies have minimized risks in industrial settings. Researchers emphasize closed-loop systems to reduce waste, aligning with circular economy principles. Such practices resonate with ESG (Environmental, Social, and Governance) benchmarks, which investors increasingly prioritize.
Market analysts project steady growth for the hafnium chemicals sector, driven by expanding semiconductor fabrication plants (fabs) and renewable energy infrastructure. The compound's niche yet indispensable role ensures ongoing R&D investment. For instance, recent patents describe novel HfCl4 delivery systems for ALD reactors, optimizing deposition uniformity—a response to the industry's push for smaller, more efficient transistors.
In summary, Tetrachlorohafnium (CAS No. 13499-05-3) exemplifies how specialized inorganic compounds underpin technological progress. Its multifaceted applications—from cutting-edge electronics to green energy—highlight the intersection of chemistry and innovation. As industries evolve toward smarter and more sustainable solutions, the strategic importance of hafnium-based precursors will only intensify, making this compound a focal point for scientific and commercial exploration.
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