Cas no 13465-58-2 (Samarium(III) sulfate octahydrate)

Samarium(III) sulfate octahydrate (Sm?(SO?)?·8H?O) is a hydrated rare earth sulfate compound with applications in catalysis, materials science, and research. Its high purity and well-defined crystalline structure make it suitable for precise synthetic and analytical processes. The octahydrate form ensures stability under standard conditions, facilitating handling and storage. Samarium(III) sulfate is valued for its role in redox reactions and as a precursor for other samarium-containing materials, including phosphors and magnetic compounds. Its solubility in water and compatibility with various solvents enhance its utility in solution-phase chemistry. The compound is typically characterized by XRD and spectroscopic methods to confirm composition and hydration state.
Samarium(III) sulfate octahydrate structure
13465-58-2 structure
Product Name:Samarium(III) sulfate octahydrate
CAS No:13465-58-2
MF:H16O20S3Sm2
MW:733.030040740967
MDL:MFCD00149862
CID:86988
PubChem ID:24859542
Update Time:2025-06-09

Samarium(III) sulfate octahydrate Chemical and Physical Properties

Names and Identifiers

    • Samarium(III) sulfate octahydrate
    • samarium (III) sulphate octahydrate
    • SamariumsulfateoctahydrateREOwhitextl
    • SAMARIUM SULFATE
    • samarium(3+),trisulfate
    • SAMARIUM SULPHATE
    • Samarium Sulphate Hydrate
    • SAMARIUM SULFATE OCTAHYDRATE
    • SAMARIUM(III) SULFATE OCTAHYDRATE 99.9&
    • Samarium Sulphate Hydrate 99.99%
    • SAMARIUM(III) SULFATE OCTAHYDRATE 99.999%
    • 3SO4.2Sm.8H2O
    • 5392AF
    • TRA0175222
    • SY011800
    • Samarium(III) sulfate octahydrate, 99.99%
    • Samarium(III) sulfate octahydrate, REacton(R)
    • Samarium(III) sulfate octahydrate, 99.9% trace metals basis
    • Sulfuric acid,samarium(3+) salt (3:2), octahydrate (8CI,9CI)
    • MFCD00149862
    • AKOS025243712
    • Samarium(III) sulfate octahydrate, REacton?
    • FT-0696541
    • samarium(3+);trisulfate;octahydrate
    • 13465-58-2
    • DISAMARIUM(3+) OCTAHYDRATE TRISULFATE
    • MDL: MFCD00149862
    • Inchi: 1S/3H2O4S.8H2O.2Sm/c3*1-5(2,3)4;;;;;;;;;;/h3*(H2,1,2,3,4);8*1H2;;/q;;;;;;;;;;;2*+3/p-6
    • InChI Key: SICAFVHZPBSARB-UHFFFAOYSA-H
    • SMILES: [Sm+3].[Sm+3].S(=O)(=O)([O-])[O-].S(=O)(=O)([O-])[O-].S(=O)(=O)([O-])[O-].O.O.O.O.O.O.O.O

Computed Properties

  • Exact Mass: 735.77900
  • Monoisotopic Mass: 591.694644
  • Isotope Atom Count: 0
  • Hydrogen Bond Donor Count: 8
  • Hydrogen Bond Acceptor Count: 20
  • Heavy Atom Count: 25
  • Rotatable Bond Count: 0
  • Complexity: 62.2
  • Covalently-Bonded Unit Count: 5
  • Defined Atom Stereocenter Count: 0
  • Undefined Atom Stereocenter Count : 0
  • Defined Bond Stereocenter Count: 0
  • Undefined Bond Stereocenter Count: 0
  • Surface Charge: 0
  • Tautomer Count: nothing
  • XLogP3: nothing
  • Topological Polar Surface Area: 274

Experimental Properties

  • Color/Form: White monoclinic crystal with hygroscopicity
  • Density: 2.93?g/mL?at 25?°C(lit.)
  • Melting Point: 450°C -8H?O
  • Boiling Point: No data available
  • Flash Point: °C
  • Water Partition Coefficient: Sparingly soluble in water
  • PSA: 339.76000
  • LogP: -1.28600
  • Sensitiveness: Sensitive to humidity
  • Solubility: Slightly soluble
  • Merck: 14,8347

Samarium(III) sulfate octahydrate Security Information

  • Symbol: GHS07
  • Signal Word:Warning
  • Hazard Statement: H315,H319,H335
  • Warning Statement: P261,P305+P351+P338
  • Hazardous Material transportation number:NONH for all modes of transport
  • WGK Germany:3
  • Hazard Category Code: 36/37/38
  • Safety Instruction: S26-S37/39
  • Hazardous Material Identification: Xi
  • TSCA:Yes
  • Risk Phrases:R36/37/38
  • Safety Term:S24/25
  • Storage Condition:Store at 4°C,-4At ℃Store…Better

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Additional information on Samarium(III) sulfate octahydrate

Samarium(III) Sulfate Octahydrate (CAS No. 13465-58-2): An Overview of Its Properties, Applications, and Recent Research

Samarium(III) sulfate octahydrate (CAS No. 13465-58-2) is a rare earth compound that has garnered significant attention in various scientific and industrial fields due to its unique properties and potential applications. This compound is a hydrated form of samarium sulfate, where samarium, a lanthanide element, is coordinated with sulfate ions and water molecules. The octahydrate form indicates that each molecule of samarium sulfate is associated with eight water molecules.

The chemical formula for samarium(III) sulfate octahydrate is Sm2(SO4)3·8H2O. This compound is known for its high solubility in water, making it suitable for various aqueous-based applications. Its molecular weight is approximately 618.44 g/mol, and it typically appears as a white crystalline solid at room temperature.

In terms of physical properties, samarium(III) sulfate octahydrate exhibits a high melting point of around 700°C and is stable under normal conditions. However, it can decompose at higher temperatures, releasing sulfur trioxide and water vapor. The compound's stability and solubility make it an attractive material for use in chemical synthesis, catalysis, and other advanced materials science applications.

One of the key areas where samarium(III) sulfate octahydrate has shown significant promise is in the field of catalysis. Recent research has demonstrated its effectiveness as a catalyst in various organic reactions, particularly those involving the activation of carbon-hydrogen bonds. For instance, a study published in the Journal of Catalysis in 2021 reported that samarium-based catalysts, including samarium(III) sulfate octahydrate, can significantly enhance the efficiency of C-H bond activation processes, leading to improved yields and selectivity in the synthesis of complex organic molecules.

Beyond catalysis, samarium(III) sulfate octahydrate has also found applications in the development of luminescent materials. Samarium ions are known for their characteristic luminescence properties, particularly in the red region of the visible spectrum. This property makes samarium(III) sulfate octahydrate a valuable component in the fabrication of phosphors and other luminescent materials used in display technologies and optical sensors.

In the biomedical field, rare earth compounds like samarium(III) sulfate octahydrate have been explored for their potential therapeutic applications. Research published in the Journal of Medicinal Chemistry in 2020 highlighted the use of samarium-based complexes as potential radiopharmaceuticals for cancer therapy. These complexes can be used to deliver targeted radiation to tumor sites, minimizing damage to healthy tissues. While more research is needed to fully understand the safety and efficacy of these compounds in clinical settings, initial results are promising.

The environmental impact of rare earth compounds, including samarium(III) sulfate octahydrate, is another area of ongoing research. Studies have shown that while these compounds are generally stable and do not pose significant environmental risks under normal conditions, their disposal and recycling must be carefully managed to prevent potential ecological harm. Efforts are being made to develop more sustainable methods for the extraction and processing of rare earth elements to minimize environmental impact.

In conclusion, samarium(III) sulfate octahydrate (CAS No. 13465-58-2) is a versatile compound with a wide range of applications in catalysis, luminescent materials, and biomedical research. Its unique properties make it an important material for advancing various scientific and industrial fields. As research continues to uncover new uses and improve our understanding of this compound, its importance is likely to grow even further.

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