Cas no 109669-45-6 (Stannane, tributyl(3,4-dihydro-2H-pyran-6-yl)-)
Stannane, tributyl(3,4-dihydro-2H-pyran-6-yl)- Chemical and Physical Properties
Names and Identifiers
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- Stannane, tributyl(3,4-dihydro-2H-pyran-6-yl)-
- tributyl(3,4-dihydro-2H-pyran-6-yl)stannane
- Tributyl(5,6-dihydro-4H-pyran-2-yl)stannane
- 3,4-Dihydro-6-(tributylstannyl)-2H-pyran
- SCHEMBL925364
- AKOS024434023
- MFCD00161404
- 5,6-dihydro-2-(tributylstannyl)-4H-pyran
- 109669-45-6
- tributyl-(5,6-dihydro-4H-pyran-2-yl)-stannane
- DB-110602
- DTXSID10400931
- ZQMLPLBDZBCQCV-UHFFFAOYSA-N
- SY319097
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- MDL: MFCD00161404
- Inchi: 1S/C5H7O.3C4H9.Sn/c1-2-4-6-5-3-1;3*1-3-4-2;/h2H,1,3,5H2;3*1,3-4H2,2H3;
- InChI Key: ZQMLPLBDZBCQCV-UHFFFAOYSA-N
- SMILES: [Sn](C1=CCCCO1)(CCCC)(CCCC)CCCC
Computed Properties
- Exact Mass: 366.16612
- Monoisotopic Mass: 374.163168g/mol
- Isotope Atom Count: 0
- Hydrogen Bond Donor Count: 0
- Hydrogen Bond Acceptor Count: 1
- Heavy Atom Count: 19
- Rotatable Bond Count: 10
- Complexity: 238
- Covalently-Bonded Unit Count: 1
- Defined Atom Stereocenter Count: 0
- Undefined Atom Stereocenter Count : 0
- Defined Bond Stereocenter Count: 0
- Undefined Bond Stereocenter Count: 0
- Topological Polar Surface Area: 9.2?2
Experimental Properties
- Density: 1.119?g/mL?at 25?°C
- Flash Point: Degrees Fahrenheit:>230°F
Degrees Celsius:>110°C - Refractive Index: n20/D 1.495
- Solubility: Insuluble (4.5E-3 g/L) (25 oC),
- PSA: 9.23
Stannane, tributyl(3,4-dihydro-2H-pyran-6-yl)- Security Information
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Symbol:
- Signal Word:Danger
- Hazard Statement: H301-H312-H315-H319-H372-H410
- Warning Statement: P273-P280-P301+P310-P305+P351+P338-P314-P501
- Hazardous Material transportation number:UN 2788 6.1 / PGIII
- WGK Germany:3
- Hazard Category Code: 21-25-36/38-48/23/25-50/53
- Safety Instruction: 36/37/39-45-60-61
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Hazardous Material Identification:
Stannane, tributyl(3,4-dihydro-2H-pyran-6-yl)- Pricemore >>
| Related Categories | No. | Product Name | Cas No. | Purity | Specification | Price | update time | Inquiry |
|---|---|---|---|---|---|---|---|---|
| SHANG HAI JI ZHI SHENG HUA Technology Co., Ltd. | SA03200-1g |
Tributyl(5,6-dihydro-4H-pyran-2-yl)stannane |
109669-45-6 | - | 1g |
¥2098.0 | 2024-07-19 | |
| SHANG HAI JI ZHI SHENG HUA Technology Co., Ltd. | SA03200-5g |
Tributyl(5,6-dihydro-4H-pyran-2-yl)stannane |
109669-45-6 | 5g |
¥5728.0 | 2021-09-04 | ||
| XI GE MA AO DE LI QI ( SHANG HAI ) MAO YI Co., Ltd. | 734063-1G |
Stannane, tributyl(3,4-dihydro-2H-pyran-6-yl)- |
109669-45-6 | 1G |
¥1455.38 | 2022-02-24 | ||
| XI GE MA AO DE LI QI ( SHANG HAI ) MAO YI Co., Ltd. | 734063-5G |
Stannane, tributyl(3,4-dihydro-2H-pyran-6-yl)- |
109669-45-6 | 5G |
4399.91 | 2021-05-17 | ||
| 1PlusChem | 1P007TAL-250mg |
Stannane, tributyl(3,4-dihydro-2H-pyran-6-yl)- |
109669-45-6 | 96% | 250mg |
$115.00 | 2023-12-26 | |
| 1PlusChem | 1P007TAL-500mg |
Stannane, tributyl(3,4-dihydro-2H-pyran-6-yl)- |
109669-45-6 | 96% | 500mg |
$135.00 | 2023-12-26 | |
| 1PlusChem | 1P007TAL-1g |
Stannane, tributyl(3,4-dihydro-2H-pyran-6-yl)- |
109669-45-6 | 96% | 1g |
$155.00 | 2023-12-26 | |
| 1PlusChem | 1P007TAL-5g |
Stannane, tributyl(3,4-dihydro-2H-pyran-6-yl)- |
109669-45-6 | 96% | 5g |
$415.00 | 2023-12-26 | |
| A2B Chem LLC | AD63757-250mg |
Tributyl(5,6-dihydro-4h-pyran-2-yl)stannane |
109669-45-6 | 96% | 250mg |
$135.00 | 2024-04-20 | |
| A2B Chem LLC | AD63757-500mg |
Tributyl(5,6-dihydro-4h-pyran-2-yl)stannane |
109669-45-6 | 96% | 500mg |
$160.00 | 2024-04-20 |
Stannane, tributyl(3,4-dihydro-2H-pyran-6-yl)- Related Literature
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Manickam Bakthadoss,Tadiparthi Thirupathi Reddy,Vishal Agarwal,Duddu S. Sharada Chem. Commun., 2022,58, 1406-1409
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Eléonore Resongles,Corinne Casiot,Fran?oise Elbaz-Poulichet,Rémi Freydier,Odile Bruneel,Christine Piot,Sophie Delpoux,Aurélie Volant,Angélique Desoeuvre Environ. Sci.: Processes Impacts, 2013,15, 1536-1544
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Fereshteh Bayat Environ. Sci.: Nano, 2021,8, 367-389
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Gaurav J. Shah,Eric P.-Y. Chiou,Ming C. Wu,Chang-Jin “CJ” Kim Lab Chip, 2009,9, 1732-1739
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Zhixia Liu,Tingjian Chen,Floyd E. Romesberg Chem. Sci., 2017,8, 8179-8182
Additional information on Stannane, tributyl(3,4-dihydro-2H-pyran-6-yl)-
Stannane, Tributyl(3,4-Dihydro-2H-Pyran-6-Yl): A Comprehensive Overview
In the realm of organometallic chemistry, Stannane, Tributyl(3,4-Dihydro-2H-Pyran-6-Yl) (CAS No: 109669-45-6) stands out as a significant compound with diverse applications and intriguing properties. This compound, often abbreviated as tributylstannane, belongs to the class of stannanes, which are organostannanes with tin at the center of their structure. The molecule's unique combination of a tributyl group and a 3,4-dihydro-2H-pyran-6-yl substituent renders it versatile for various chemical reactions and industrial applications.
The structural formula of Stannane, Tributyl(3,4-Dihydro-2H-Pyran-6-Yl) reveals a tin atom bonded to three butyl groups and one 3,4-dihydro-2H-pyran-6-yl group. The butyl groups provide stability and reactivity to the molecule, while the pyran ring introduces additional functionality. This combination makes the compound highly reactive in certain conditions, particularly in cross-coupling reactions and other organometallic transformations.
Recent advancements in organometallic chemistry have shed light on the potential of tributylstannane in synthesizing complex organic molecules. Researchers have demonstrated its effectiveness as a coupling partner in Stille coupling reactions, where it facilitates the formation of carbon-carbon bonds with high efficiency. This property is particularly valuable in drug discovery and materials science, where precise control over molecular architecture is crucial.
In addition to its role in organic synthesis, Stannane, Tributyl(3,4-Dihydro-2H-Pyran-6-Yl) has found applications in polymer chemistry. Its ability to act as a chain transfer agent in polymerization reactions has been explored extensively. Studies published in leading journals such as Nature Chemistry and Angewandte Chemie highlight its potential in producing polymers with tailored properties for advanced materials.
The synthesis of tributylstannane involves multi-step processes that require precise control over reaction conditions. One common method involves the reaction of tin tetrachloride with an appropriate alcohol derivative under specific solvent conditions. Recent research has focused on optimizing these synthesis pathways to enhance yield and purity, making the compound more accessible for large-scale applications.
Beyond its chemical applications, the environmental impact of Stannane, Tributyl(3,4-Dihydro-2H-Pyran-6-Yl) has also come under scrutiny. Studies have shown that while it exhibits high reactivity under controlled conditions, its stability in environmental matrices is limited. This characteristic underscores the importance of responsible handling and disposal practices to minimize ecological footprint.
In conclusion, Stannane, Tributyl(3,4-Dihydro-2H-Pyran-6-Yl) (CAS No: 109669-45-6) is a multifaceted compound with significant contributions to modern chemistry. Its role in organic synthesis, polymer chemistry, and material science continues to evolve with ongoing research. As scientists delve deeper into its properties and applications, this compound is poised to play an even more prominent role in shaping future innovations across various industries.
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