• 1. Fast synthesis of copper nanoclusters through the use of hydrogen peroxide additive and their application for the fluorescence detection of Hg2+ in water samples?
  Liao Xiaoqing,Li Ruiyi,Li Zaijun,Sun Xiulan,Wang Zhouping,Liu Junkang New J. Chem., 2015,39, 5240-5248
• 2. EWOD-driven droplet microfluidic device integrated with optoelectronic tweezers as an automated platform for cellular isolation and analysis?
  Gaurav J. Shah,Eric P.-Y. Chiou,Ming C. Wu,Chang-Jin “CJ” Kim Lab Chip, 2009,9, 1732-1739
• 3. Embedding cyclic nitrone in mesoporous silica particles for EPR spin trapping of superoxide and other radicals?
  Eric Besson,Stéphane Gastaldi,Emily Bloch,Selma Aslan,Hakim Karoui,Olivier Ouari,Micael Hardy Analyst, 2019,144, 4194-4203
• 4. Fate of single walled carbon nanotubes in wetland ecosystems?
  Joseph H. Bisesi,Tara Sabo-Attwood Environ. Sci.: Nano, 2014,1, 574-583
• 5. Evolution of hierarchical porous structures in supramolecular guest–host hydrogels?
  Christopher B. Rodell,Christopher B. Highley,Minna H. Chen,Neville N. Dusaj,Chao Wang,Lin Han,Jason A. Burdick Soft Matter, 2016,12, 7839-7847

• Solvents and Organic Chemicals Organic Compounds Organoheterocyclic compounds Thiophenes 2,5-disubstituted thiophenes

5-Methyl-2-Tributylstannylthiophene: A Comprehensive Overview

5-Methyl-2-Tributylstannylthiophene (CAS No. 107311-67-1) is a unique organometallic compound that has garnered significant attention in the fields of organic electronics, materials science, and catalysis. This compound is a derivative of thiophene, a heterocyclic aromatic compound, with a methyl group at the 5-position and a tributylstannyl group at the 2-position. The combination of these substituents imparts distinctive electronic and structural properties, making it a valuable material for various applications.

The tributylstannyl group in 5-Methyl-2-Tributylstannylthiophene plays a crucial role in its chemical behavior. Stannane groups are known for their ability to act as electron donors, which can significantly influence the electronic properties of the parent thiophene ring. Recent studies have demonstrated that this compound exhibits enhanced conductivity and stability under certain conditions, making it a promising candidate for use in organic semiconductors and flexible electronics. Researchers have also explored its potential as a precursor for the synthesis of more complex organometallic compounds.

One of the most notable applications of 5-Methyl-2-Tributylstannylthiophene is in the field of materials science. Its ability to form self-assembled monolayers (SAMs) has been extensively studied, with findings suggesting that these SAMs can be utilized in the development of advanced sensors and nanoscale devices. The methyl group at the 5-position contributes to the compound's hydrophobicity, which is advantageous for certain sensing applications where water resistance is critical.

In terms of synthesis, 5-Methyl-2-Tributylstannylthiophene is typically prepared through a two-step process involving the alkylation of thiophene followed by stannylation. Recent advancements in catalytic methods have enabled more efficient and selective syntheses, reducing production costs and improving yield. These improvements have made the compound more accessible for both academic research and industrial applications.

From an environmental standpoint, 5-Methyl-2-Tributylstannylthiophene has been evaluated for its biodegradability and toxicity. Studies indicate that it exhibits low toxicity to aquatic organisms under standard test conditions, which aligns with its potential use in eco-friendly materials. However, further research is required to fully understand its long-term environmental impact.

Looking ahead, 5-Methyl-2-Tributylstannylthiophene holds immense potential for innovation in several areas. Its role as an intermediate in the synthesis of advanced materials, such as perovskite solar cells and organic light-emitting diodes (OLEDs), is being actively explored. Additionally, its unique electronic properties make it a strong candidate for use in next-generation catalytic systems, where it could facilitate more efficient chemical transformations.

In conclusion, 5-Methyl-2-Tributylstannylthiophene (CAS No. 107311-67-1) is a versatile organometallic compound with a wide range of applications across multiple disciplines. Its distinctive structure and properties continue to drive cutting-edge research, positioning it as a key material for future technological advancements.

• 162717-58-0(Stannane, [2,2'-bithiophen]-5-yltributyl-)
• 171290-94-1(5,5'-Bis(tributylstannyl)-2,2'-bithiophene)
• 388616-36-2(Stannane, tributyl(5-pentyl-2-thienyl)-)
• 54663-78-4(2-(Tributylstannyl)thiophene)
• 388616-37-3(Stannane, tributyl(5-hexyl-2-thienyl)-)
• 214044-46-9(Stannane, tributyl[2,2':5',2''-terthiophen]-5-yl-)
• 144968-82-1(2-Thiophenecarboxaldehyde, 5-(tributylstannyl)-)
• 388616-42-0(Stannane, tributyl(5-dodecyl-2-thienyl)-)
• 388616-38-4(Stannane, tributyl(5-heptyl-2-thienyl)-)
• 388616-40-8(Stannane, tributyl(5-nonyl-2-thienyl)-)