Cas no 1066-78-0 (Tetrakis(diethylamino)tin)
Tetrakis(diethylamino)tin Chemical and Physical Properties
Names and Identifiers
-
- tetrakis(dimethylamino)tin
- Tetrakis(Diethylamine)Tin
- 397326_ALDRICH
- AG-D-21269
- CTK4A4707
- Stannanetetramine, octaethyl-
- Tetrakis(diethylamido)tin(IV)
- TETRAKIS(DIETHYLAMINO)TIN
- Tetrakis(diethylamino)tin(IV)
- TIN (IV) DIETHYLAMIDE
- OCTAMETHYLSTANNANETETRAAMINE
- N-ethyl-N-[tris(diethylamino)stannyl]ethanamine
- tetrakis-(diethylamino)-stannane
- 941T968
- N,N,N',N',N'',N'',N''',N'''-Octaethylstannanetetramine
- N,N,N',N',N'',N'',N''',N'''-octaethylstannanetetraamine
- MFCD00239515
- 21941-96-8
- 1066-78-0
- DTXSID80586837
- Tetrakis(diethylamino) tin(IV)
- SCHEMBL4831599
- AKOS025293701
- Tetrakis(diethylamino)tin
-
- MDL： MFCD00239515
- Inchi： 1S/4C4H10N.Sn/c4*1-3-5-4-2;/h4*3-4H2,1-2H3;/q4*-1;+4
- InChI Key： IFVSPCQTOMZHOP-UHFFFAOYSA-N
- SMILES： [Sn](N(C([H])([H])C([H])([H])[H])C([H])([H])C([H])([H])[H])(N(C([H])([H])C([H])([H])[H])C([H])([H])C([H])([H])[H])(N(C([H])([H])C([H])([H])[H])C([H])([H])C([H])([H])[H])N(C([H])([H])C([H])([H])[H])C([H])([H])C([H])([H])[H]
Computed Properties
- Exact Mass: 408.227500 g/mol
- Monoisotopic Mass: 408.227500 g/mol
- Isotope Atom Count: 0
- Hydrogen Bond Donor Count: 0
- Hydrogen Bond Acceptor Count: 4
- Heavy Atom Count: 21
- Rotatable Bond Count: 12
- Complexity: 193
- Covalently-Bonded Unit Count: 1
- Defined Atom Stereocenter Count: 0
- Undefined Atom Stereocenter Count : 0
- Defined Bond Stereocenter Count: 0
- Undefined Bond Stereocenter Count: 0
- Topological Polar Surface Area: 13
- Surface Charge: 0
- Tautomer Count: nothing
- XLogP3: nothing
- Molecular Weight: 407.2
Experimental Properties
- Color/Form: Clear liquid
- Density: 1.125?g/mL?at 25?°C(lit.)
- Melting Point: Not available
- Boiling Point: 110?°C/0.5?mmHg(lit.)
- Flash Point: Fahrenheit: 102.2 ° f
Celsius: 39 ° c - Refractive Index: n20/D 1.49(lit.)
- Solubility: Not determined
- Vapor Pressure: 0.0±0.8 mmHg at 25°C
Tetrakis(diethylamino)tin Security Information
-
Symbol:
- Signal Word：Danger
- Hazard Statement： H226-H301-H311-H318-H331
- Warning Statement： P261-P280-P301+P310-P305+P351+P338-P311
- Hazardous Material transportation number：UN 2929 6.1/PG 2
- WGK Germany：3
- Hazard Category Code： 10-14-23/24/25-41
- Safety Instruction： 16-26-36/37/39-45
-
Hazardous Material Identification：
- TSCA：No
- Storage Condition：storage at -4℃ (1-2weeks), longer storage period at -20℃ (1-2years)
Tetrakis(diethylamino)tin Pricemore >>
| Related Categories | No. | Product Name | Cas No. | Purity | Specification | Price | update time | Inquiry |
|---|---|---|---|---|---|---|---|---|
| XI GE MA AO DE LI QI （ SHANG HAI ） MAO YI Co., Ltd. | 397326-5G |
Tetrakis(diethylamino)tin |
1066-78-0 | 5G |
￥2016.45 | 2022-02-24 |
Tetrakis(diethylamino)tin Related Literature
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Liao Xiaoqing,Li Ruiyi,Li Zaijun,Sun Xiulan,Wang Zhouping,Liu Junkang New J. Chem., 2015,39, 5240-5248
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Olga Guselnikova,Gérard Audran,Jean-Patrick Joly,Andrii Trelin,Evgeny V. Tretyakov,Vaclav Svorcik,Oleksiy Lyutakov,Sylvain R. A. Marque Chem. Sci., 2021,12, 4154-4161
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Maomao Hou,Fenglin Zhong,Qiu Jin,Enjiang Liu,Jie Feng,Tengyun Wang,Yue Gao RSC Adv., 2017,7, 34392-34400
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Domenico Lombardo,Gianmarco Munaò,Pietro Calandra,Luigi Pasqua,Maria Teresa Caccamo Phys. Chem. Chem. Phys., 2019,21, 11983-11991
Additional information on Tetrakis(diethylamino)tin
Introduction to Tetrakis(diethylamino)tin (CAS No. 1066-78-0)
Tetrakis(diethylamino)tin, with the chemical formula C??H??N?Sn and CAS number 1066-78-0, is a significant compound in the field of organotin chemistry. This organotin derivative is characterized by its four diethylamino groups attached to a tin center, making it a versatile reagent in synthetic chemistry. The compound's unique structure and properties have garnered considerable attention in both academic research and industrial applications.
The synthesis of Tetrakis(diethylamino)tin involves the reaction of stannic chloride with diethylamine in an inert atmosphere, typically under reflux conditions. This process ensures the formation of a stable complex where the tin atom is coordinated to four diethylamino ligands. The reaction is highly sensitive to moisture and air, necessitating anhydrous conditions and inert gas protection. Despite these challenges, the compound's high reactivity makes it a valuable intermediate in various chemical transformations.
In recent years, Tetrakis(diethylamino)tin has been extensively studied for its role in cross-coupling reactions, particularly in the pharmaceutical and materials science sectors. One of the most notable applications is its use as a catalyst in the Stille coupling reaction, where it facilitates the formation of carbon-carbon bonds between organotin reagents and organic halides. This reaction is crucial for the synthesis of complex organic molecules, including those found in active pharmaceutical ingredients (APIs).
Recent advancements in synthetic methodologies have highlighted the compound's utility in constructing biaryl structures, which are prevalent in many biologically active compounds. For instance, researchers have utilized Tetrakis(diethylamino)tin to develop novel antifungal agents and anti-inflammatory drugs. The ability to efficiently form biaryl linkages has opened new avenues for drug discovery, leveraging the compound's catalytic prowess.
The compound's stability under various reaction conditions also makes it suitable for large-scale industrial processes. Its compatibility with a wide range of substrates and solvents enhances its practicality in manufacturing environments. Additionally, efforts have been made to optimize its use through green chemistry principles, aiming to reduce waste and improve energy efficiency in synthetic routes.
From a materials science perspective, Tetrakis(diethylamino)tin has been explored for its potential in polymer synthesis and functional material development. Its ability to act as a cross-linking agent has been exploited in creating novel polymers with enhanced mechanical and thermal properties. These materials find applications in coatings, adhesives, and advanced composites, demonstrating the compound's broad utility beyond traditional organic synthesis.
The compound's interaction with biological systems has also been a subject of interest. While organotin compounds are generally known for their biological activity, Tetrakis(diethylamino)tin's specific effects are still under investigation. Preliminary studies suggest that it may exhibit properties relevant to neurochemistry and developmental biology, although further research is needed to fully understand its biological profile.
In conclusion, Tetrakis(diethylamino)tin (CAS No. 1066-78-0) is a multifaceted compound with significant implications in synthetic chemistry, pharmaceuticals, and materials science. Its role as a catalyst in cross-coupling reactions and its potential applications in drug development and advanced materials underscore its importance. As research continues to uncover new uses for this organotin derivative, its impact on various scientific fields is likely to grow even further.
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